1988
DOI: 10.1007/bf01913932
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Kinetic-morphological peculiarities of solid-state isomerization of complexes

Abstract: The thermal solid-state isomerizations of Copy2Cl 2 (py = pyridine), Nien2(NO2) 2 and Nien2(NCS) 2 (en = ethylenediamine) were studied by thermal analysis, thermomieroscopy, Xray diffraction and IR-speetroscopy. It was shown that the reactions proceed by nuclear formation and growth. The kinetic-morphological peculiarities of the processes suggest that the process-determining stage is a phase Stage, i. e. structural transformation. The topography and kinetics of processes are therefore determined by the crysta… Show more

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Cited by 5 publications
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“…This is a classical process well described in the literature. 17,18 However, the nucleation sites grow anisotropically. Significant isomerisation (darkening) is initially localised (pictures 4 and 5), followed by anisotropic interface advance (mainly along crystal edges, pictures 6-9) that combines with nucleation sites that have hitherto experienced only limited growth.…”
Section: Resultsmentioning
confidence: 99%
“…This is a classical process well described in the literature. 17,18 However, the nucleation sites grow anisotropically. Significant isomerisation (darkening) is initially localised (pictures 4 and 5), followed by anisotropic interface advance (mainly along crystal edges, pictures 6-9) that combines with nucleation sites that have hitherto experienced only limited growth.…”
Section: Resultsmentioning
confidence: 99%