The N(⁴S) + N₂O(X̃¹∑) reaction

Abstract

The title reaction, which is spin-forbidden for production,has been studied from 960 to 1130 K in a high-temperature photochemistry reactor. No re-

Theoretical calculations and anahrmonic effect analysis for the conversion of nitrogen radical in burning reaction

“…At last, in order to verify this work, the rate constants by this calculation were compared with Femandes' experiment data. [ 65 ] It can be seen that the references and the calculations were more and more close as the temperature increased.…”

An Experimental and Theoretical Investigation of the Gas-Phase C(3P) + N2O Reaction. Low Temperature Rate Constants and Astrochemical Implications

“…While the neutral–neutral reactions of C and N atoms with NO molecules are reasonably well characterized at low temperature through several experimental and theoretical studies − (the reaction between ground state atomic oxygen and nitric oxide occurs through three body association, which will be negligible at the densities of interstellar clouds), there are very few studies of gas-phase N 2 O reactions at interstellar temperatures. In terms of its reactivity toward atomic radicals, N 2 O is not expected to react with N or O atoms at low temperature (the N + N 2 O reaction is spin forbidden while the O + N 2 O reaction is characterized by a large activation barrier). In contrast, the reactivity of atomic carbon toward N 2 O has been studied at room temperature by the Husain group , using the flash photolysis of carbon suboxide as a source of ground state atomic carbon with these atoms being detected by resonance absorption around 166 nm.…”