Abstract:The purpose of this research is that clearly comprehends the conversion and reaction mechanism of N radical in burning reaction. The harmonic and anharmonic rate constants of the related reactions were calculated by the transition state (TS) theory and Yao and Lin (YL) method. And the kinetic and thermodynamic parameters considering anharmonic and harmonic factor were fitted respectively. In conclusion, the anharmonic effect cannot be ignored on the reaction process of N radical conversion. Besides, the simula… Show more
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