“…Because of the known structure (for Ag 29 (BDT) 12 TPP 4 NCs), stability, and highly emissive nature (for Ag 29 (DHLA) 12 NCs), a large variety of Ag 29 NCs with different primary and secondary ligands have been reported focusing on their structure and PL properties making this Ag 29 the most studied silver NC so far. [44][45][46][47][48][49][50] While several reviews and perspectives have covered metal NCs and their properties, 1,2,25,[51][52][53][54][55][56][57][58][59][60][61][62][63][64] no such review highlights the importance of the ligand effect on atomically precise silver NCs. This is primarily because of a lack of reports on single atomically precise AgNCs with a variety of ligands, unlike the case of Au 25 NCs.…”