Abstract:In the present study, the distribution patterns of various metals were analyzed and compared using PM samples collected concurrently from three monitoring sites located in Korea (Seoul, Busan, and Jeju island) in December 2002. As these sites can represent metal pollution with different degrees of anthropogenic activities, their concentration levels were distinguished in a systematic manner in the order of Jeju, Busan, and Seoul. By comparing the present data sets with those measured previously from other loca… Show more
“…The metal concentrations (ng m -3 ) in Kanpur were also found in the considerably high range of 300-6170 (Fe), 200-1630 (Zn), 70-1030 (Pb), 2-43 (Cd), 32-400 (Cr), and 40-270 (Ni) (during 2002-2003) [44]. Except for Fe, Cu, Ba, and Mn, the metal concentrations in this study were about two to six times lower than those measured in Seoul during winter 2002 [45]. As seen in Table 5, the mean Pb and Ni concentration levels at all four sites in the present study of 67.6 and 9.59 ng m -3 , respectively, are around three and five times less than 200 (Pb) and 46.3 ng m -3 (Ni) at Sejong University, Seoul in December 2002 [44].…”
Section: Comparison With Previous Studiescontrasting
Concentrations of 17 trace metals bound in total suspended particulate (TSP) were measured at four urban residential locations (Jong Ro [JR], Gwang Jin [GJ], Gang Seo [GS], and Yang Jae [YJ]) in Seoul, Korea from February to July 2009. The maximum concentrations of metals were recorded by Fe in the range of 2599 (JR) to 2914 ng m-3 (GJ), while the least values were observed from Ag or Co with a few ng m-3. The relative ordering of the mean concentration (ng m-3) at these sites is generally found on the order of Fe > Zn > Ba > Mn > Pb > Cu > B > Cr > Ni > Sr >V > As > Li > Cd > Mo > Co > Ag or with a few exceptions (e.g., a reversal between Ba and Mn or between Ni and Sr). Calculation of the enrichment factor suggests the significant role of man-made processes on such metals as Cd, Zn, and Pb. Inspection of the temporal patterns indicates the peak occurrence of most metals during the spring season due in part to the Asian Dust (AD) event. However, according to the factor analysis, sources of these metals were dominated by both resuspended soil/road dust and the combustion of fossil fuels. The overall results of our study suggest that the interaction between the environmental conditions and roadside traffic activities are paramount in explaining the metal pollution in these urban residential areas.
“…The metal concentrations (ng m -3 ) in Kanpur were also found in the considerably high range of 300-6170 (Fe), 200-1630 (Zn), 70-1030 (Pb), 2-43 (Cd), 32-400 (Cr), and 40-270 (Ni) (during 2002-2003) [44]. Except for Fe, Cu, Ba, and Mn, the metal concentrations in this study were about two to six times lower than those measured in Seoul during winter 2002 [45]. As seen in Table 5, the mean Pb and Ni concentration levels at all four sites in the present study of 67.6 and 9.59 ng m -3 , respectively, are around three and five times less than 200 (Pb) and 46.3 ng m -3 (Ni) at Sejong University, Seoul in December 2002 [44].…”
Section: Comparison With Previous Studiescontrasting
Concentrations of 17 trace metals bound in total suspended particulate (TSP) were measured at four urban residential locations (Jong Ro [JR], Gwang Jin [GJ], Gang Seo [GS], and Yang Jae [YJ]) in Seoul, Korea from February to July 2009. The maximum concentrations of metals were recorded by Fe in the range of 2599 (JR) to 2914 ng m-3 (GJ), while the least values were observed from Ag or Co with a few ng m-3. The relative ordering of the mean concentration (ng m-3) at these sites is generally found on the order of Fe > Zn > Ba > Mn > Pb > Cu > B > Cr > Ni > Sr >V > As > Li > Cd > Mo > Co > Ag or with a few exceptions (e.g., a reversal between Ba and Mn or between Ni and Sr). Calculation of the enrichment factor suggests the significant role of man-made processes on such metals as Cd, Zn, and Pb. Inspection of the temporal patterns indicates the peak occurrence of most metals during the spring season due in part to the Asian Dust (AD) event. However, according to the factor analysis, sources of these metals were dominated by both resuspended soil/road dust and the combustion of fossil fuels. The overall results of our study suggest that the interaction between the environmental conditions and roadside traffic activities are paramount in explaining the metal pollution in these urban residential areas.
“…The number of ports with cargo handling capacity more than one hundred million tons per year had reached to 22 by 2010, half of which are located in the Bohai Rim (Report on China Shipping Development, 2010). The concentration of vanadium (often referred to emissions from heavy oil) in PM 2.5 observed at Jeju Island in Korea had been rapidly risen from 1.1 to 8.5 ng·m −3 during 2001 to 2006 (Kim et al, 2006;Moon et al, 2008;Nguyen et al, 2009). Vanadium concentration largely attributed to the increase of ship emission around the sea waters.…”
“…For example, the concentration of V increased from 2.4 ng m -3 in 2008 to 4.9 ng m -3 in 2009-2010 in Tianjin, China (Gu et al, 2011;Zhao et al, 2013), and increased from 13 ng m -3 in 2002 to 70 ng m -3 in 2011-2012 in Qingdao (Guo et al, 2004;Wu et al, 2013). In Korea, the concentration of V in PM 2.5 observed in Jeju Island increased rapidly from 1.1 ng m -3 in 2001 to 8.5 ng m -3 in 2006 (Kim et al, 2006;Moon et al, 2008;Nguyen et al, 2009). The observed concentration of V for the port of Rotterdam showed significant decrease due to the ban of HFO use by ships since 2008 because fuels now in use contain much less sulfur and vanadium (Visschedijk et al, 2013).…”
Shipping emissions potentially contribute to the degradation of air quality in port cities. In this study, PM 2.5 samples were collected from two sites at different distances from the shipping channel of Xiamen Port in southeastern China between November 2015 and May 2018 and analyzed for their chemical compositions, which included water-soluble ions, carbonaceous species, and elements. The average annual PM 2.5 mass concentrations were 55.8 ± 22.7 µg m -3 and 56.5 ± 24.5 µg m -3 at the urban and suburban sites, respectively, with the lowest values in summer and the highest in winter/spring. Significantly higher values for vanadium (V) and nickel (Ni) were found at the urban site due to the shorter distance between this location and the shipping channel. Using a PMF model, six source factors were identified: sulfate and shipping emissions (16.6-20.9%), secondary nitrate and chloride (14.7-17.3%), fugitive dust (16.9-23.0%), industrial emissions (5.5-7.0%), primary organic aerosol (14.1-14.8%), and traffic emissions and biomass burning (23.8-24.6%). Potential source contribution function analysis indicated that air masses from the South China Sea contributed significantly to the shipping emissions. The PMF-based method did not distinguish primary shipping emissions from secondary sulfate. When a V-based method was used, the primary PM 2.5 from shipping emissions plus its associated secondary sulfate was shown to contribute 5.5-8.9% of the ambient PM 2.5 on average. The results from the V-based method exhibited strong positive correlations with those of the PMF-based method. Considering the potential negative effect on air quality and the expanding international maritime trade in the long term, our research indicates that policies and regulations for controlling shipping emissions are necessary in all major port cities, including those outside the domestic emission control areas of China.
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