The metal–organic framework HKUST-1 as efficient sorbent in a vortex-assisted dispersive micro solid-phase extraction of parabens from environmental waters, cosmetic creams, and human urine

Rocío‐Bautista, Priscilla; Martínez-Benito, Carla; Pino, Verónica; Pasán, Jorge; Ayala, Juan H.; Ruíz-Pérez, Catalina; Afonso, Ana M.

doi:10.1016/j.talanta.2015.02.032

Cited by 155 publications

(39 citation statements)

References 53 publications

(55 reference statements)

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“…This method significantly reduces the amount of sample used. Rocío‐Bautista and co‐workers detected parabens in environmental waters, cosmetic creams, and human urine. HKUST‐1 was synthesized and used as a sorbent for μ‐SPE.…”

Section: Application Of Mofs For Sample Preparationmentioning

confidence: 99%

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Wang

2017

Electrophoresis

108

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In the field of analytical chemistry, sample preparation and chromatographic separation are two core procedures. The means by which to improve the sensitivity, selectivity and detection limit of a method have become a topic of great interest. Recently, porous organic frameworks, such as metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), have been widely used in this research area because of their special features, and different methods have been developed. This review summarizes the applications of MOFs and COFs in sample preparation and chromatographic stationary phases. The MOF- or COF-based solid-phase extraction (SPE), solid-phase microextraction (SPME), gas chromatography (GC), high-performance liquid chromatography (HPLC) and capillary electrochromatography (CEC) methods are described. The excellent properties of MOFs and COFs have resulted in intense interest in exploring their performance and mechanisms for sample preparation and chromatographic separation.

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Section: Application Of Mofs For Sample Preparationmentioning

confidence: 99%

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Wang

2017

Electrophoresis

108

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“…Another work on MOF HKUST‐1 (Hong Kong University of Science and Technology) which was made up of copper nodes with 1,3,5‐benzenetricarboxylic acid struts between them, was reported by Rocio‐Bautista et al. but in different application. The MOF was a new class of organic–inorganic microporous crystalline materials self‐assembled directly from metal ions with organic linkers by coordination bonds.…”

Section: Application Of Organic–inorganic Hybrid‐based Adsorbents In mentioning

confidence: 99%

Advances in organic–inorganic hybrid sorbents for the extraction of organic and inorganic pollutants in different types of food and environmental samples

Kamaruddin

Ibrahim

et al. 2017

J of Separation Science

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The efficiency of the extraction and removal of pollutants from food and the environment has been an important issue in analytical science. By incorporating inorganic species into an organic matrix, a new material known as an organic-inorganic hybrid material is formed. As it possesses high selectivity, permeability, and mechanical and chemical stabilities, organic-inorganic hybrid materials constitute an emerging research field and have become popular to serve as sorbents in various separaton science methods. Here, we review recent significant advances in analytical solid-phase extraction employing organic-inorganic composite/nanocomposite sorbents for the extraction of organic and inorganic pollutants from various types of food and environmental matrices. The physicochemical characteristics, extraction properties, and analytical performances of sorbents are discussed; including morphology and surface characteristics, types of functional groups, interaction mechanism, selectivity and sensitivity, accuracy, and regeneration abilities. Organic-inorganic hybrid sorbents combined with extraction techniques are highly promising for sample preparation of various food and environmental matrixes with analytes at trace levels.

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“…Ten milligrams of as-prepared ZIF-8@CoFe 2 O 4 material was placed in a 15 mL glass vial, then, 5 mL of CR (30, 60, 90, and 120 mg/L) or BR2 dye (4,8,12,16, and 20 mg/L) aqueous solution of different concentration was added to the vial and sonicated for 15 min at room temperature at pH of 7.…”

Section: Mspe Of Cr and Br2mentioning

confidence: 99%

“…Metal-organic frameworks (MOFs), as an emerging class of crystalline materials, built upon coordinated metal ions and organic ligands, possess many unique properties such as tunable pore sizes and high specific surfaces, making MOFs promising for diverse applications, especially, in environmental purification [11][12][13][14][15][16][17][18][19][20][21]. Recently, considerable researches have been reported focusing on development of MOF-based SPE methods for a great variety of analytes, including estrogenic drugs [11,12], polybrominated diphenyl ethers [13], and bisphenols [14], etc.…”

Section: Introductionmentioning

confidence: 99%

Rapid magnetic solid‐phase extraction of Congo Red and Basic Red 2 from aqueous solution by ZIF‐8@CoFe₂O₄ hybrid composites

Jin

et al. 2016

J of Separation Science

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Core-shell metal-organic framework materials have attracted considerable attention mainly due to their enhanced or new physicochemical properties compared with their single-component counterparts. In this work, a core-shell heterostructure of CoFe2 O4 -Zeolitic Imidazolate Framework-8 (ZIF-8@CoFe2 O4 ) is successfully fabricated and used as an solid-phase extraction adsorbent to efficiently extract Congo Red and Basic Red 2 dyes from contaminated aqueous solution. Vibrating sample magnetometry indicates that the saturated magnetization of ZIF-8@CoFe2 O4 is 3.3 emu/g, which is large enough for magnetic separation. The obtained hybrid magnetic metal-organic framework based material ZIF-8@CoFe2 O4 can remove the investigated dyes very fast within 1 min of the contact time. The adsorbent ZIF-8@CoFe2 O4 also shows a good reusability. After regeneration, the adsorbent can still exhibit high removal efficiency (∼97%) toward Congo Red for five cycles of desorption-adsorption. This work reveals the great potential of core-shell ZIF-8@CoFe2 O4 sorbents for the fast separation and preconcentration of organic pollutants in aqueous solution before high-performance liquid chromatography analysis.

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The metal–organic framework HKUST-1 as efficient sorbent in a vortex-assisted dispersive micro solid-phase extraction of parabens from environmental waters, cosmetic creams, and human urine

Cited by 155 publications

References 53 publications

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Advances in organic–inorganic hybrid sorbents for the extraction of organic and inorganic pollutants in different types of food and environmental samples

Rapid magnetic solid‐phase extraction of Congo Red and Basic Red 2 from aqueous solution by ZIF‐8@CoFe₂O₄ hybrid composites

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The metal–organic framework HKUST-1 as efficient sorbent in a vortex-assisted dispersive micro solid-phase extraction of parabens from environmental waters, cosmetic creams, and human urine

Cited by 155 publications

References 53 publications

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Recent advances in metal‐organic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis

Advances in organic–inorganic hybrid sorbents for the extraction of organic and inorganic pollutants in different types of food and environmental samples

Rapid magnetic solid‐phase extraction of Congo Red and Basic Red 2 from aqueous solution by ZIF‐8@CoFe2O4 hybrid composites

Contact Info

Product

Resources

About

Rapid magnetic solid‐phase extraction of Congo Red and Basic Red 2 from aqueous solution by ZIF‐8@CoFe₂O₄ hybrid composites