The Intercalation Reaction of 1,10-Phenanthroline with Layered Compound FePS3

Magnetic measurements on an intercalate Fe0.9PS3(Phen)0.4: an ESR study

“…Its structure was characterised by elemental analysis, infrared spectroscopy and X-ray powder diffraction techniques [5]. A conventional X-band ð f D9:7 GHzÞ Bruker EMX model spectrometer employing an AC magnetic field modulation technique was used to record the first derivative absorption signal as a function of temperature between 9 and 300 K: Fig.…”

Charge compensation in a layered van der Waals NiPS3 host through various cationic intercalations

“…For instance, it was reported that there is a strong tendency in MnPS 3 and FePS 3 for cation exchange, along with the creation of M 2+ vacancies during intercalation. 15,16,19–21 In contrast, no direct intercalation of pyridine was observed for NiPS 3 , although metal-to-ligand interaction would be of a similar bond strength. 22 Pattayil et al suggested that a possible reason for this is the difference in the crystal field energy, which stabilizes Ni in the crystal structure, 22 thereby impeding the pyridine intercalation.…”

Formation of composite nanomaterial MnPS3 layered structure intercalated with pyridine

“…where G is the guest ionic species [24][25][26][27]. The charge balance of these compounds has been maintained by the loss of one M 2+ ion from the intralayer region for every two guest ions (G + ) that are inserted and located in the interlayer space.…”