2000
DOI: 10.1006/jssc.2000.8879
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The Intercalation of Some Heterocyclic Amines into α-Titanium Hydrogenphosphate—Structural and Calorimetric Data

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Cited by 30 publications
(17 citation statements)
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“…Thus, a plot of P X/ P Dh r vs. P X gives Dh int and K values from the angular and linear coefficients, respectively, after linearization of the equation, as shown in figure 4. and the number of moles of amine adsorbed after the calorimetric equilibrium is reached on the inorganic matrix n s , then, the enthalpy of interaction can be calculated by: DH = Dh int /n s , where 1/Dh int = b, that is angular coefficient obtained in figure 4, with n s being calculated from the batch process intercalation results [10,11,15,17,18]. It is worth mentioning that investigations involving calorimetric techniques to detect the thermal effects associated with intercalation processes are rare and this investigation deals with endeavors to increase the data available for such kinds of systems.…”
Section: Resultsmentioning
confidence: 99%
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“…Thus, a plot of P X/ P Dh r vs. P X gives Dh int and K values from the angular and linear coefficients, respectively, after linearization of the equation, as shown in figure 4. and the number of moles of amine adsorbed after the calorimetric equilibrium is reached on the inorganic matrix n s , then, the enthalpy of interaction can be calculated by: DH = Dh int /n s , where 1/Dh int = b, that is angular coefficient obtained in figure 4, with n s being calculated from the batch process intercalation results [10,11,15,17,18]. It is worth mentioning that investigations involving calorimetric techniques to detect the thermal effects associated with intercalation processes are rare and this investigation deals with endeavors to increase the data available for such kinds of systems.…”
Section: Resultsmentioning
confidence: 99%
“…In such a case, a sequence of values was obtained from the calorimetric data to enable the calculation of the enthalpy of intercalation to form the monolayer per unit of mass of the host, Dh int , by using equation (4). The modified Langmuir equation was adapted to describe several types of systems [17] …”
Section: Resultsmentioning
confidence: 99%
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“…The same procedure for the isotherms of time and concentration was used to calculate the number of moles of the metallic cation adsorbed per gram (N f ), which is given by the difference between the initial (N i ) and the remaining number of moles of metal in the supernatant (N s ), divided by the mass (m) of the compound used, [17][18][19][20] as given in equation 1.…”
Section: Adsorptionmentioning
confidence: 99%
“…From the experimental point of view, a calorimetric technique was applied to the heterogeneous system and the interactive effect that occurred at the (solid + liquid) interface can be determined [21][22][23]. Examples of previous investigations have focussed upon some reactions involving alkylmonoamines [16], n-alkyldiamines [24], and some aromatic heterocyclic amines [25,26] with a-titanium hydrogenphosphate. Data on a series of n-alkylmonoamines with barium phosphate system are now presented.…”
Section: Introductionmentioning
confidence: 99%