“…Copper-based compounds are included in “protectant” multi-site fungicides that are used in pre-infection applications to form a protective barrier at the plant surface. This group includes dithiocarbamates such as mancozeb, zineb, maneb, propamocarb, metiram, propineb (Clifford and Bruyns-Haylett, 1978 ; Falk et al, 1996 ; Gisi, 2002 ; Šrobárová et al, 2007 ; Gisi and Sierotzki, 2008 ; Patil, 2015 ); phthalimide group, represented by captan, captafol, and folpet (O'Neill et al, 1996 ; Madden et al, 2000 ; Genet et al, 2006 ; Rekanovic et al, 2008 ; Gullino et al, 2010 ; Jermini et al, 2010a ; Gessler et al, 2011 ; Barros et al, 2018 ); phthalonitrile chlorothalonil (Northover and Ripley, 1980 ; Gisi et al, 2007 ; Lebeda et al, 2008 ; Barros et al, 2018 ) and quinone dithianon (Corio-Costet, 2011 ; Nanni et al, 2016 ). Phenylamides and aluminum are two of the most broadly applied systemic fungicides to manage P. viticola .…”