-The application of biochar to soils because of beneficial effects is proven by many international researchers and this can increase herbicides sorption and reduce effectiveness on weed management. Positive impacts are reported in relation to the environmental behavior of herbicides, since the increase of the sorption reduces the leaching of these products to groundwater. Negative impacts are reported in relation to agronomic management of herbicides, since the sorption increase reduces the availability of these products in the soil, reducing the residual effect for weed control. In Brazil, biochar is produced by several private companies and pyrolysis units, but the cost for production is still very high, probably due to lack of government incentive, low use of producers, and awareness of the benefits. Although biochar has been used for several decades in other countries, in Brazil there are still few studies developed by soil researchers, and biochar efficiency on the bioavailability of herbicide in the soil is still unknown by many weed science Brazilian researchers. Against the above, the objective of this review was to evaluate the bioavailability of herbicides in biochar-amended soils and highlight the research with biochar in Brazilian conditions, besides presenting the benefits to soil with biochar addition. Little is known about the herbicides behavior in Brazilian soils amended with biochar, which can be used with greater intensity in modern agriculture. So more research is needed under our conditions to really we understand the dynamics of this product in the soil. Keywords: black carbon, retention, management practices, soil behavior Resumo -A aplicação de biochar (biocarvão) em solos por causa dos efeitos benéficos é comprovada por muitos pesquisadores internacionais e isto pode aumentar a sorção dos herbicidas e reduzir a eficácia destes no manejo das plantas daninhas. Impactos positivos são relatados em relação ao comportamento ambiental dos herbicidas, pois o aumento da sorção reduz a lixiviação destes produtos para as águas subterrâneas. Impactos negativos são relatados em relação ao manejo agronômico dos herbicidas, pois o aumento da sorção reduz a disponibilidade destes produtos no solo, diminuindo o efeito residual para o controle das plantas daninhas. No Brasil, o biochar é produzido por várias empresas privadas e unidades de pirólise, entretanto, o custo para produção ainda é muito alto, Mendes et al. Rev. Bras. Herb