Abstract:We report a joint experimental and theoretical study on the stability and reactivity of Bi n + (n = 5-33) clusters. The alternating odd-even effect on the reaction rates of Bi n + clusters with NO is observed, and Bi 7 + finds the most inertness. First-principles calculation results reveal that the lowest energy structures of Bi 6-9+ exhibit quasi-spherical geometry pertaining to the jellium shell model; however, the Bi n + (n � 10) clusters adopt assembly structures. The prominent stability of Bi 7+ is associ… Show more
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