Carbonate minerals are common gangue minerals in the low sulfidation epithermal Au-Ag District of El Peñón, II Región, Chile. They can be subdivided into two principal groups on the basis of the paragenetic relationships. Paragenetically early carbonates occur together with quartz and sulfide minerals in banded veins and are closely associated with precious metal mineralization. These carbonates are compositionally complex, consisting of calcite, finely intermixed with ankerite, kutnohorite, rhodochrosite and dolomite, but also contain up to 0.8 wt% PbCO 3 and up to 4.1 wt% ZnCO 3 . In contrast, the paragenetically late carbonates are relatively pure calcite, although dolomite has been recognized locally. Late calcites contain less than 3.5 wt% MnCO 3 , less than 0.5 wt% ZnCO 3 and less than 2.7 wt% FeCO 3 and are also distinct from the early carbonates in that they exhibit moderate to intense red fluorescence under short-wave ultraviolet light. O values for two of the late calcites and oxygen isotopic data of vein quartz from earlier studies suggest precipitation from a meteoric fluid, the heavy isotopic signature of most carbonates indicates that the mineralizing fluid was overall heterogeneous. δ 13 C values range between -8.9‰ and +1.5‰ relative to the Pee Dee Belemnite (VPDB) standard and are consistent with a meteoric or magmatic origin, in some samples probably with a minor contribution of organic carbon. Periodic involvement of a fluid with a strong magmatic component or, alternatively, meteoric water which has undergone extensive evaporation probably played an important role in the hydrothermal system. The complex stable isotope signature of El Peñón is interpreted as indicative for arid climatic conditions as a meteoric origin of the fluid is not as evident as in similar deposits emplaced in more pluvial regions.
RESUMENCarbonatos en vetas en el distrito epitermal de baja sulfuración de El Peñón, II Región, Chile: ambiente de formación e implicancias para la exploración. En el distrito epitermal de Au-Ag de baja sulfuración de El Peñón, II Región, Chile, los carbonatos son minerales de ganga comunes. Estos minerales pueden ser subdivididos en dos grupos principales sobre la base de sus relaciones paragenéticas. Carbonatos paragenéticamente tempranos se encuentran junto a cuarzo y sulfuros en vetas bandeadas y están estrechamente asociados con la mineralización de metales preciosos. Estos carbonatos son composicionalmente complejos, consistiendo en calcita entrecrecida con ankerita, kutnohorita, rhodocrosita y dolomita, pero también contienen hasta 0,8% en peso de PbCO 3 y hasta 4,1% en peso de ZnCO 3 . En contraste, los carbonatos paragenéticamente tardíos son calcita relativamente pura, aunque localmente también se ha reconocido dolomita. Las calcitas tardías contienen menos de 3,5% en peso MnCO 3 , menos de 0,5% en peso de ZnCO 3 y menos de 2,7% en peso de FeCO 3 y también son distintas a los carbonatos tempranos en que se caracterizan por una fluorescencia roja moderada a intensa bajo luz ...