The flexibility of binding modes of the supersilyl thiolate ligand SSitBu3−

Meyer-Wegner, Frank; Bolte, Michael; Lerner, Hans‐Wolfram

doi:10.1016/j.inoche.2012.11.033

Inorganic Chemistry Communications

2013

DOI: 10.1016/j.inoche.2012.11.033

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The flexibility of binding modes of the supersilyl thiolate ligand SSitBu3−

Frank Meyer-Wegner¹,

Michael Bolte²,

Hans‐Wolfram Lerner³

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Cited by 8 publications

(1 citation statement)

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“…[28] Unusual stable trisilanols were tested for the inhibition of acetylcholinesterase. [32] The luminescence and magnetic properties of metal complexes with soft silanethiolate ligands have also been studied. However, silicon chalcogenides have been applied as reagents in organic syntheses, [30,31] and metal complexes with silyl chalcogenolate ligands have been used as precursors of metal chalcogenide nanoparticles.…”

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The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

et al. 2015

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The silicon–sulfur compound bis‐1,3‐[di(2,6‐diisopropylphenoxy)]disiloxane‐1,3‐dithiol was obtained from silicon disulfide and 2,6‐diisopropylphenol in a reaction catalyzed by imidazole or 4‐(dimethylamino)pyridine (DMAP). The disiloxane‐1,3‐dithiol is produced in a low yield but in a repeatable manner and can be isolated as colorless crystals. The X‐ray crystal structure of the compound reveals a linear or close‐to‐linear Si–O–Si angle and a mutual trans position of the two hydrosulfido groups. The compound forms a chelating mononuclear complex with cadmium ions. In the complex, the sulfido groups adopt a cis conformation, and the Si–O–Siangle deviates from linearity. The molecular structure of the compound is discussed on the basis of DFT calculations.

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The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

et al. 2015

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SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S

Zámostná

Braun

2014

Angewandte Chemie

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The degradation of SF 6 and SF 5 organyls by S À F and S À C bond-activation reactions at [{Rh(m-H)(dippp)} 2 ] under mild conditions is reported. Fluorido and thiolato species were identified as products or intermediates, and were characterized by X-ray diffraction analysis and multinuclear NMR spectroscopy. An unprecedented cyclic process for the conversion of the potent greenhouse gas SF 6 into H 2 S was developed.

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SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S

Zámostná

Braun

2014

Angew Chem Int Ed

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The degradation of SF6 and SF5 organyls by S-F and S-C bond-activation reactions at [{Rh(μ-H)(dippp)}2] under mild conditions is reported. Fluorido and thiolato species were identified as products or intermediates, and were characterized by X-ray diffraction analysis and multinuclear NMR spectroscopy. An unprecedented cyclic process for the conversion of the potent greenhouse gas SF6 into H2S was developed.

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The flexibility of binding modes of the supersilyl thiolate ligand SSitBu3−

Cited by 8 publications

References 16 publications

The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S

SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S

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The flexibility of binding modes of the supersilyl thiolate ligand SSitBu3−

Cited by 8 publications

References 16 publications

The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

The Syntheses and Crystal Structures of the First Disiloxane‐1,3‐dithiol and Its Cadmium Complex

SF and SC Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S

SF and SC Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S

Contact Info

Product

Resources

About

SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S

SF and SC Activation of SF₆ and SF₅ Derivatives at Rhodium: Conversion of SF₆ into H₂S