The first coordination compounds of OP[NC₄H₈O]₃phosphoric triamide ligand: structural study and Hirshfeld surface analysis of Sn^IVand Mn^IIcomplexes

Structural, Hirshfeld surface and molecular docking studies of a new organotin(IV)-phosphoric triamide complex and an amidophosphoric acid ester proposed as possible SARS-CoV-2 and Monkeypox inhibitors

“…Such secondary and tertiary N atoms with a low Lewis-base character cannot be involved in any hydrogen bond interaction as an acceptor. The Sn–O, Sn–Cl and Sn–C bond lengths and the Sn–O–P bond angles ( Table S1 ) are within the expected values [ 7 , 50 ].…”

Chiral phosphoric triamide‐based polymers for enantioseparation

“…Phosphoramides with a P(O)(N) segment are attractive to study owing to their extensive applications in the coordination chemistry, catalysts, and medicine . From our previous studies on phosphorus‐oxygen, phosphorus‐nitrogen, and phosphorus‐sulfur compounds, the PO group was found as the best hydrogen‐bond acceptor with respect to the other possible acceptor groups, which usually exist in the molecules, typically CO, SO, N─O, PS, ester and ether oxygen atoms, nitrogen, and π‐system, examined with X‐ray diffraction study, statistical analysis based on the data deposited in the Cambridge structural database (CSD) and quantum chemical calculations in some cases.…”