The Evaluation of the Mathematical Model of Interaction of Electrochemically Activated Water Solutions (Anolyte and Catholyte) with Water

Abstract

This paper deals with the evaluation of the basis of the mathematical model of interaction of electrochemically activated water solutions (catholyte/anolyte), obtained in the diaphragm electrolysis cell, with water and sodium chloride and the basic physical-chemical processes underlying the electrolysis of water as well. In order to provide additional data about the distribution of H 2 O molecules according to the energies of hydrogen bonds in the electrochemically activated water solutions of the catholyte and the anolyte, the non-equilibrium energy spectrum 72 European Reviews of Chemical Research, 2015, Vol.(4), Is. 2 (NES) and differential non-equilibrium energy spectrum (DNES) of the anolyte and the catholyte were measured as a result of which were established the basis for evaluation of the mathematical model explaining the behavior of the anolyte and the catholyte regarding the distribution of H 2 O molecules to the energies of hydrogen bonds. The local maximum for catholyte in the NESspectrum was at -0,1285 eV, for anolyte -at -0,1227 eV and for the control sample of deionized water -at -0,1245 eV. The calculations of ∆E H...O for catholyte with using the DNES method compiles (-0,004±0,0011 eV) and for anolyte (+1,8±0,0011 eV). The average energy of hydrogen bonds between Н 2 О molecules was measured by the DNES method to be compiled at -0,1067±0,0011 eV.Keywords: electrochemical treatment of water, electrolysis, anolyte, catholyte, NES, DNES. IntroductionThe phenomenon of electrochemical activation of water (EAW) is a set of electrochemical and electrical processes occur in water in the electric double layer (EDL) type of electrodes (anode and cathode) with non-equilibrium electric charge transfer through EDL by electrons under the intensive dispersion in water the gaseous products of electrochemical reactions [1]. In 1985 EAW was officially recognized as a new class of physical and chemical phenomena.As a result of the treatment of water by a constant electric current at electric potentials equal to or greater than the decomposition potential of water (1,25 V), water goes into a metastable state, accompanied by electrochemical processes and characterized by the abnormal activity levels of electrons, the redox potential, and other physical-chemical parameters (pH, Eh, ORP) [2].During the EAW occur four main processes: 1) Electrolytical decomposition of water by electrolysis on account of redox reactions on the electrodes due to the external electric field;2) Electrophoresis -the movement in the electric field of a positively charged particles and ions toward the cathode and negatively charged particles and ions toward the anode;3) Electroflotation -the gas formation and flocculation of aggregates consisting of finedispersed gas bubbles (H 2 at the cathode and O 2 at the anode) and suspended solids in water; 4) Electrocoagulation -the formation of colloidal aggregates of particles of deposited disperse phase through a process of anode dissolution of the metal and the formation of metal cations Al...

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