The Essential Oil of<i>Calamintha arkansana</i>(Nutt.) Shinners

Tucker, Arthur O.; Maciarello, Michael J.

doi:10.1080/10412905.1991.9697924

Cited by 8 publications

(1 citation statement)

References 3 publications

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“…Geranylbarium (77), which can be obtained209 by reacting geranyl chloride (78) with equirnolar Reike barium in tetrahydrofuran at -78 "C, can be coupled with the geraniolderived bromide (79) to yield geranylgeraniol (80) without disturbance of alkene geometry.210 After appropriate chemistry, the sequence can be repeated to synthesise higher homologues. Citronella1 (53) reacts rapidly with diethanolamine to give (81) which undergoes hydration and then hydrolysis in the presence of sulfuric acid to give the hydroxy-aldehyde (82) without significant competing cyclisation.211 Reaction of (R)citronellyl acetate (83) with thionyl chloride at -20 "C in the presence of catalytic Et2A1C1 and then with methanol yields the rearranged allylic sulfinate ester (84) via an ene-type process. Geranyl and linalyl acetates behave analogously.212 Linalool (25) reacts with thiourea in the presence of hydrohalic acids to give geranyl thiol (85) after basic hydrolysis of the thiouronium salt which is formed.213…”

Section: I ! Nmentioning

confidence: 99%

Monoterpenoids

Grayson¹

1996

Nat. Prod. Rep.

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Cymbopogon coloratus Cymbopogon distans Cym bopogon t ra vanco rensis Egletes viscosa Erigeron canadensis Eucalyptus bicostata Eucalyptus brassiana S. T. Blake Eucalypt us b r idgesian a Eucalyptus camaldulensis Eucalyptus dealbata Eucalyptus delg up ta Eucalyptus torelliana Eupatorium adenophorum Spring. Ferulago sylvatica (Besser) Reichenb. Foeniculum vulgare Forsythia spp. Gardenia jasminoides Geranium robertianum Grindelia robusta Nutt. Grindelia squarrosa Dun. Hedychium coronarium Hedychium coronarium Koenig Hedychium odoratissimum Helichrysum picardii Heteropyxis natalensis Hjwopus oficinalis Juniperus sabina Kaunea longipetolia Lanata camara Lepechinia urbanii (Briq.) Epling Lepidophyllum quadrangulare (Meyen) Libanotis laticalycina Shan et Sheh. Liquidambar orientalis Mill. Litsea pungens Hemsl. Lonicera japonica Thunb. Magnolia coco (Lour) DC. Benth. and Hook.

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Section: I ! Nmentioning

confidence: 99%

Monoterpenoids

Grayson¹

1996

Nat. Prod. Rep.

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The volatile constituents of Acinus alpinus (L.) Moench ssp. meridionalis (Nyman) P. W. Ball growing in Spain

Velasco‐Negueruela

Pérez‐Alonso

Jiménez

et al. 1993

Flavour & Fragrance J

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Analysis of two samples of the oil of Acinus alpinus (L.) Moench subsp. meridionalis (Nyman) P. W. Ball revealed the following composition: monoterpene hydrocarbons (6.1 70, 14.1%), oxygenated monoterpenes (1.7%. 1.9"/0), sesquiterpene hydrocarbons (83.1%, 79.3%) and oxygenated sesquiterpenes (9.1Y0, 4.7%). The main constituents found were germacrene-D (56.8%, 43.2%), rram-p-caryophyllene (6.2%, 15.4%) and bicyclogermacrene (s.90/,, 11.7%). KEY WORDS Acinus alpinus ( L . ) Moench subsp. meridionalis (Nyman) P. W. Ball Lamiaceae Volatile oil Sesquiterpenes Germacrene-D tram-p-Caryophyllene Bicyclogermacrene.

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