In recent years, a new type ER fluids named as polar-molecule-dominated electrorheological (PM-ER) fluids have been developed, of which the yield stress can reach more than 100 kPa and behaves a linear dependence on the electric field. A brief description on the composition and synthesizing method for the materials is given. The main merits of PM-ER fluid are as follows: high yield stress, the shear stress increasing with shear rate up to more than 10 3 s −1 , low current density, rapid electric response and anti-sedimentation. Some perspectives on PM-ER fluid and its applications are presented.