The Effect of Unsaturation on the Activity of Alcoholic Hydroxyl. I. Action of Allyl Alcohol on Benzene in the Presence of Aluminum Chloride

Huston, R. C.; Sager, D.

doi:10.1021/ja01418a024

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1931

1984

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Cited by 7 publications

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Essais de Chloration Dirigée: XIII. La Photochloration Directe des Hydrocarbures Arylaliphatiques [1]

Corbiau

Bruylants

1970

Bulletin des Soc Chimique

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Photochlorination in liquid phase was performed at various temperatures (from 22 to 98°C) in order to determine the ratio of the various monochlorinated isomers generated during the reaction. The different compounds studied are of general formula C6H5R, where R is equal to: C2H5, n.C3H7, i.C3H7, n.C4H9, sec. C4H9, n.C5H11. Substitution only takes place in the side chain and preferentially in the α position: for instance, ethylbenzene gave 90% of the α and 10% of the β‐chloroethylbenzene. Differences between activation energy of the two chlorinations of the same hydrocarbon are relatively high. In the case of C2H5C6H5 the value (Eα ‐ Eβ) amounts 3.130 cal. m−1.

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Essais de Chloration Dirigée: XIII. La Photochloration Directe des Hydrocarbures Arylaliphatiques [1]

Corbiau

Bruylants

1970

Bulletin des Soc Chimique

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The catalytic decomposition of 4‐phenyl‐1,3‐dioxan on copper‐based catalysts

Červený

Wurzlová

Marhoul

et al. 1984

J. Chem. Tech. Biotechnol.

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Transformations of 4‐phenyl‐1,3‐dioxan on copper‐based catalysts were investigated in an integral flow reactor in the gas phase in the temperature range 220–280°C. The main products of splitting were 3‐phenylpropanal, 3‐phenylpropan‐1‐ol and allylbenzene, and in some cases, styrene. Suitable reaction conditions were sought for the preparation of 3‐phenylpropanal and allylbenzene from 4‐phenyl‐1,3‐dioxan.

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The polymerization of allylbenzene with lewis acids: A polyalkylation reaction

Davidson

1966

J. Polym. Sci. B Polym. Lett.

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The Effect of Unsaturation on the Activity of Alcoholic Hydroxyl. I. Action of Allyl Alcohol on Benzene in the Presence of Aluminum Chloride

Cited by 7 publications

References 0 publications

Essais de Chloration Dirigée: XIII. La Photochloration Directe des Hydrocarbures Arylaliphatiques [1]

Essais de Chloration Dirigée: XIII. La Photochloration Directe des Hydrocarbures Arylaliphatiques [1]

The catalytic decomposition of 4‐phenyl‐1,3‐dioxan on copper‐based catalysts

The polymerization of allylbenzene with lewis acids: A polyalkylation reaction

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