The Effect of Mechanochemical and Ultrasonic Treatments on the Properties of Composition CeO2–MoO3 = 1:1

Zazhigalov, V. A.; Diyuk, O. A.; Sachuk, O. V.; Diyuk, N. V.; Starchevsky, V. L.; Sawłowicz, Zbigniew; Bacherikova, I. V.; Щербаков, С. М.

doi:10.1007/978-3-030-17759-1_8

Cited by 5 publications

(2 citation statements)

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“…A H 2 temperature programmed reduction (TPR) study was performed in a H 2 –Ar medium (H 2 /Ar = 1:1) in the temperature range of 30–800 °C with a heating rate of 5 °C/min, mixture feed rate of 80 mL/min, catalyst weight of 50 mg, scale sensitivity of 3.4 × 10 –5 g, and data registration rate of 10 points/min. The scheme and operation conditions of the device are published elsewhere …”

Section: Methodsmentioning

confidence: 99%

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Graphitic Carbon Nitride as a Sustainable Catalyst for Selective Ethanol Oxidation

Shcherban

Diyuk

Zazhigalov

et al. 2021

ACS Sustainable Chem. Eng.

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Graphitic carbon nitride (g-C 3 N 4 ) is obtained via a simple procedure consisting of melamine heating in air without any templates and additional treatments. The prepared g-C 3 N 4 , being a metal-free material, demonstrates a promising catalytic performance for the selective oxidation of ethanol yielding acetaldehyde (conversion of ethanol up to 100%, yield of acetaldehyde up to 69%). In the investigated reaction conditions, a large content of C− NC species results in an enhanced selectivity toward acetaldehyde, while an increased content of tertiary nitrogen leads to the intensification of side product formation. Graphitic carbon nitride demonstrates high productivity for acetaldehyde and excellent stability without any deactivation.

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Section: Methodsmentioning

confidence: 99%

“…The scheme and operation conditions of the device are published elsewhere. 36 Catalytic Tests. Catalytic activity of the prepared metal-free materials in the oxidation of ethanol was investigated in a flow fixedbed stainless steel reactor in the temperature range of 100−400 °C at atmospheric pressure.…”

Section: ■ Materials and Methodsmentioning

confidence: 99%