The effect of ligand basicity on the thermal stability of heterodinuclear NiII–ZnII complexes

N,N'-Bis(Salisiliden)-1,3-Propandiamin Schiff Bazının Agregasyon Kaynaklı Emisyon Artışı

“…Karışım kaynama noktasına kadar ısıtıldıktan sonra 3-4 saat oda sıcaklığında bekletildi. Elde edilen sarı kristaller süzüldükten sonra havada kurutuldu[20]. Bu ligandın sentezine ait reaksiyon Şekil 1'de verilmiştir.…”

DNA cleavage activities and mechanism of a novel heterodinuclear macrocyclic complex

“…Although the DNA cleavage activities and mechanisms of a few homodinuclear macrocyclic complexes [10,11] and some heterodinuclear uncyclic complexes [12][13][14] have been studied, the DNA cleavage studies of the heterodinuclear complexes of tetraazamacrocyclic dicompartmental ligands have not been reported yet. Herein, in order to find the more efficient DNA cleavage agent and discuss the synergistic effect in the processes of the cleavage, we have designed and synthesized a heterodinuclear Cu(II)Zn(II) complex of tetraazamacrocyclic dicompartmental ligand with two furan pendants.…”