The effect of heavy water on the chemical shift of F19

Borodin, P. M.; Legin, E. K.; Sventitskii, E. N.; Khusidman, M.B.; Щербаков, В. А.

doi:10.1007/bf00746632

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Vbhv1

E Ion Association1

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1967

1975

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Cited by 6 publications

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“…The addition of D20 to HF-H20 solutions causes a high-field shift in the F19 nmr (40). In 50% D20-50% H20 solutions a downfield shift with increasing HF concentration is observed reflecting the accumulation of DF molecules as the HF concentration increases.…”

Section: Vbhvmentioning

confidence: 94%

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Nuclear Magnetic Resonance Studies of Ions in Pure and Mixed Solvents

Hinton¹,

Amis²

1967

Chem. Rev.

118

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Section: Vbhvmentioning

confidence: 94%

“…It was suggested that this might be due to ion association. The F19 nmr has been found to shift to high fields in solutions of KF-H20 in which increasing amounts of D20 are added (40). This phenomenon is thought to be due to enhanced ion-pair formation on the addition of D20.…”

Section: E Ion Associationmentioning

confidence: 96%