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citations
Cited by 111 publications
(42 citation statements)
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References 202 publications
(384 reference statements)
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“…There has been renewed interest in the solvation of simple anions, such as the halides, with protic solvents [1][2][3][4][5][6][7][8][9][10]. The strength of alcoholhalide interactions have been shown by IR spectroscopy [1,2] to depend upon the anion in the order F-> Cl-> Br->I-, as was also observed by NMR methods [3].…”
Section: Lbl-1630mentioning
confidence: 99%
See 1 more Smart Citation
“…There has been renewed interest in the solvation of simple anions, such as the halides, with protic solvents [1][2][3][4][5][6][7][8][9][10]. The strength of alcoholhalide interactions have been shown by IR spectroscopy [1,2] to depend upon the anion in the order F-> Cl-> Br->I-, as was also observed by NMR methods [3].…”
Section: Lbl-1630mentioning
confidence: 99%
“…A study of UV and IR spectra suggested that the solvation number of the tetrahexylammonium iodide-alcohol complex was unity [6]. The hydration numbers of the halides as determined in aqueous solution by NMR methods [7,8] are 1.6 for F-, 0-2 for Cl-, and 1 for. Br-.…”
Section: Lbl-1630mentioning
confidence: 99%
“…Evaluation of a,, is of considerable importance, since the electrostatic contribution to the chemical shift is needed in studies of ionic hydration (20). In the past, a,, has been estimated (21) or assumed to be equal to a,,; it appears that this may have led to an underestimate of the polarization contribution to hydration shifts.…”
Section: Chen7ical Shqt In the Complexmentioning
confidence: 99%
“…Early reports described solution behavior of alkali metal salts in water (1)(2)(3)(4). These salts remained dissociated and solvated until salt concentrations approached 5 to 15 molal (1, 2).…”
Section: Introductionmentioning
confidence: 99%