The effect of electron donors on the polymerization of vinyl chloride with alkylboron

Borsini, Giancarlo; Cipolla, M.

doi:10.1002/pol.1964.110020309

Search citation statements

Order By: Relevance

Paper Sections

Select...

Organoboron Systems1

Organoboron-mediated Free Radical Polymerizations1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1967

2024

Publication Types

Select...

Article6

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 12 publications

(2 citation statements)

References 7 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…However, excess amounts of these compounds would retard the polymerization, as these compounds could also act as inhibitors. 44 Trialkylboron compounds. Alkylborane with a specific structure can mediate pseudo-living radical polymerization.…”

Section: Organoboron Systemsmentioning

confidence: 99%

See 1 more Smart Citation

Organoboron-mediated polymerizations

Zhang,

Yang,

et al. 2024

Chem. Soc. Rev.

View full text Add to dashboard Cite

show abstract

Section: Organoboron Systemsmentioning

confidence: 99%

“…However, excess amounts of these compounds would retard the polymerization, as these compounds could also act as inhibitors. 44…”

Section: Organoboron-mediated Free Radical Polymerizationsmentioning

confidence: 99%

Organoboron-mediated polymerizations

Zhang,

Yang,

et al. 2024

Chem. Soc. Rev.

View full text Add to dashboard Cite

show abstract

Methyl methacrylate polymerization initiated by triethylborane–peroxide mixtures

Contreras

Grotewold

Lissi

et al. 1969

J. Polym. Sci. A‐1 Polym. Chem.

View full text Add to dashboard Cite

The polymerization of methyl methacrylate initiated by triethylborane or triethylborane–peroxide mixtures was studied. The rate of initiation by a mixture of triethylborane and tert‐butyl peroxide was found to be first‐order in peroxide. The order in triethylborane changes from one at low triethylborane/peroxide to nearly zero at high triethylborane/peroxide. The possibility of a mechanism involving a fast reaction followed by a slow reaction that would initiate the polymerization is discussed.

show abstract