Abstract:The effect of Al, a trivalent substitution was investigated in Co doped ZnO with regards to the role of additional carriers in n-type magnetic semiconductors. Nanoparticle samples of Zn1?xCo0.04AlxO with different Al compositions (x = 0, 0.005, 0.010, 0.015 and 0.020) were annealed at 600 oC for different time (5 hours and 8 hours) and different gas flow rates (25 sccm and 50 sccm). All nanoparticles attained Wurtzite hexagonal structure in a stable form after annealing in forming gas. The effect of annealing … Show more
“…As ionic radius is increased from calcium to barium, the activation energies of samples are decreased from LCFMO to LBFMO. The activation energy for oxides ionic conductors is generally more than 0.9 eV, while for n-type polaronic conduction of electrons it is less than 0.2 eV and for polaronic conduction of holes it is more than 0.2 eV [38,39]. In our case, p-type polaronic conduction of holes is observed.…”
The polycrystalline double perovskites La2-xAxFeMnO6 (A = Ca, Sr, Ba; x = 0.0, 0.4) were synthesized through citrate sol-gel auto-combustion technique. The structural, optical, and electrical properties were studied by x-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy at room temperature, while electrical and dielectric measurements were evaluated at temperature ranges from 303 to 423 K. The XRD analysis through Rietveld refinement suggests the single phase orthorhombic (Pnma) symmetry for all the synthesized samples. The infrared reflectivity (IR) spectra were obtained from Fourier Transform Infrared spectroscopy (FTIR) measurements. The spectra were fitted by Lorentz oscillator model, to observe the optical phonon modes. The activation energies were calculated by DC resistivity measurements. According to the resistivity measurement the samples shows the semiconducting nature. The temperature dependent dielectric constant and tangent-loss with varying frequency are measured and discussed.
“…As ionic radius is increased from calcium to barium, the activation energies of samples are decreased from LCFMO to LBFMO. The activation energy for oxides ionic conductors is generally more than 0.9 eV, while for n-type polaronic conduction of electrons it is less than 0.2 eV and for polaronic conduction of holes it is more than 0.2 eV [38,39]. In our case, p-type polaronic conduction of holes is observed.…”
The polycrystalline double perovskites La2-xAxFeMnO6 (A = Ca, Sr, Ba; x = 0.0, 0.4) were synthesized through citrate sol-gel auto-combustion technique. The structural, optical, and electrical properties were studied by x-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy at room temperature, while electrical and dielectric measurements were evaluated at temperature ranges from 303 to 423 K. The XRD analysis through Rietveld refinement suggests the single phase orthorhombic (Pnma) symmetry for all the synthesized samples. The infrared reflectivity (IR) spectra were obtained from Fourier Transform Infrared spectroscopy (FTIR) measurements. The spectra were fitted by Lorentz oscillator model, to observe the optical phonon modes. The activation energies were calculated by DC resistivity measurements. According to the resistivity measurement the samples shows the semiconducting nature. The temperature dependent dielectric constant and tangent-loss with varying frequency are measured and discussed.
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