The Development of a Mathematical Model for the Prediction of Corrosion Rate Behaviour for Mild Steel in 0.5 M Sulphuric Acid

Abstract

The effect of varying temperature, concentration, and time on the corrosion rate of mild steel in 0.5 M H 2 SO 4 acid with and without (wild jute tree) grewia venusta plant extract has been investigated by weight loss. The temperature, concentration of inhibitor and time were varied in the range of 0-10% v/v at 2% v/v interval, 30-70 ∘ C at 20 ∘ C interval, and 45-270 minutes at 45 minutes interval respectively. Scanning electron microscope was used to analyze the morphology of the sample surface. Linear regression equation and analysis of variance (ANOVA) were employed to investigate the influence of process parameters on the corrosion rate of the samples. The predicted corrosion rate of the samples was found to lie close to those experimentally observed ones. The confirmation of the experiment conducted using ANOVA to verify the optimal testing parameters shows that the increase in inhibitor concentration above 2% v/v and time would reduce the corrosion rate. The results also showed that the increase in temperature would also increase the corrosion rate greatly and that the plant extract was very effective for the corrosion inhibition of mild steel in acidic medium.

The effect of time variation on the steels corrosion rate in 0.5 M H2SO4 solution

“…The corrosion rate increases with the increase in the corrosion time as shown in Figure 3. This result is similar to the previous studies [9], [16]. Stainless steel has the lowest weight loss with a value of 300mg and the lowest corrosion rate of 22.63 mpy.…”

Progress on pharmaceutical drugs, plant extracts and ionic liquids as corrosion inhibitors

“…Some prominent compounds such as benzoic acid [49] , benzotriazole [50] , thiourea [48] , flavonoids [51] , carbohydrates [52] , tannins [53] and tryptamine [54] containing these active functional groups whose sources are from natural plants had been applied as corrosion inhibitors for many metals. Flavin mononucleotide from grape pomace extracts was detected as a good OGCI for hot rolled steel in acidic medium [51] .…”

“… Mixed inhibitor corrosion inhibition action. [54] Anthocleista djalonesis Iridoid glucoside (djalonenoside), Dibenzo-α-pyrone (djalonensone), ursolic acid, 3-oxo-Δ-4,5-sitosterone. - [62] Guar gum Polysaccharide mainly sugars galactose and mannose 1,4-linked mannose residues linear chain forming short side branches which later formed complexes on metal surface to inhibit corrosion.…”