The determination of the standard potential of the silver‐silver bromide and the silver‐silver iodide electrode in a 87.68 wt% methanol‐water mixture and in 100% methanol

Alfenaar, M.; Ligny, C.L. De; Remijnse, A. G.

doi:10.1002/recl.19670860510

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1967

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Cited by 10 publications

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Activity coefficients of individual ions

Alfenaar

Ligny

1967

Recl. Trav. Chim. Pays‐Bas

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Existing methods for the estimation of the primary medium effect for individual ions are critically reviewed and an improved method for its estimation is developed.By this method the primary medium effect of the hydrogen ion has been determined for the transfer from water to methanol-water mixtures and methanol. The medium elfect of the alkali and the halide ions are then also known.The accuracy of the values so obtained for the individual ions is of the same order as the accuracy of experimentally determined values for electroneutral combinations of ions.

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Activity coefficients of individual ions

Alfenaar

Ligny

1967

Recl. Trav. Chim. Pays‐Bas

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The diffusion potential between electrolyte solutions in different solvents: Some quantitative data about the contribution of the transport of solvent molecules through the boundary layer to the diffusion potential

Alfenaar

Ligny

Remijnse

1967

Recl. Trav. Chim. Pays‐Bas

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In the diffusion through the boundary layer between electrolyte solutions in diferent media, the transport of uncharged particles comes into play. The contribution of this transport to the diffusion potential is measured for alkali halide solutions in methanol-water mixtures. Using A$-values of individual ions in methanol-water mixtures, the total diffusion potentials are calculated.It can be concluded that the diffusion potential between electrolyte solutions in different solvents depends mainly on the primary medium effect.

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