The Determination of the Stability Constants Binary Complexes of Alizarin with Mg (II) and Al(III) by Potentiometrie and Spectrophotometric Methods

Bilgiç, D.; Bapli, Ihsan

doi:10.1515/revac.2008.27.4.251

Reviews in Analytical Chemistry

2008

DOI: 10.1515/revac.2008.27.4.251

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The Determination of the Stability Constants Binary Complexes of Alizarin with Mg (II) and Al(III) by Potentiometrie and Spectrophotometric Methods

D. Bilgiç¹,

Ihsan Bapli²

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Cited by 3 publications

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A Plant Dye for Photocatalytic Methane Conversion

Wang

et al. 2023

Chemistry A European J

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Photocatalysis has emerged as a promising approach for aerobic methane (CH4) oxidation, but most current photocatalysts rely on metal centers. On the other hand, the excited states of many cost‐effective organic photosensitizers have short lifetimes, which limits their interaction with CH4 for the reaction to occur. To overcome this, we utilized a pre‐associated dye‐Cl‐ complex with a short‐lived excited state to efficiently generate active radical for CH4 conversion. By using an organic plant dye, alizarin (AQ), together with trifluoroacetic acid (TFA) and Cl‐, we selectively converted CH4 to methyl (CH3TFA) and methylene ditrifluoroacetate (CH2(TFA)2) using molecular oxygen (O2) as the oxidant and visible light of 420 nm. This study demonstrates the potential of using affordable organic dyes and halide supramolecular chemistry for scalable CH4 photo‐conversion, opening up exciting avenues for future research.

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A Plant Dye for Photocatalytic Methane Conversion

Wang

et al. 2023

Chemistry A European J

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Separation of 9,10-anthraquinone derivatives: Evaluation of C18 stationary phases

Bonose¹,

Nowik²,

Tchapla³

et al. 2011

Journal of Chromatography A

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Al(III) complexation by alizarin studied by electronic spectroscopy and quantum chemical calculations

Say-Liang-Fat

Cornard

2011

Polyhedron

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The Determination of the Stability Constants Binary Complexes of Alizarin with Mg (II) and Al(III) by Potentiometrie and Spectrophotometric Methods

Cited by 3 publications

References 6 publications

A Plant Dye for Photocatalytic Methane Conversion

A Plant Dye for Photocatalytic Methane Conversion

Separation of 9,10-anthraquinone derivatives: Evaluation of C18 stationary phases

Al(III) complexation by alizarin studied by electronic spectroscopy and quantum chemical calculations

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