The Crystal and Molecular Structure of the Diacetone Adduct of the Copper(II) Complex of 1-Nitroso-2-naphthol: [Cu(C10H6NO2)2].2(CH3)2CO..

Saarinen, Heikki; Korvenranta, Jorma; JACOBSEN, J. P.; Granberg, Mats; Karlsson, Fred; Edlund, Kaj; Eliasen, Mogens; Herskind, Carsten; Laursen, Thomas; Pedersen, Poul Møller

doi:10.3891/acta.chem.scand.29a-0409

“…Thus, A8 is referred to as a 1-nitroso-2-naphthol (or 1,2-naphthoquinone-1-oxime) complex, and A9 is the related 2-nitroso-1-naphthol complex. Several examples for A8 , where the metal is Ru [1.22−1.28 Å], , Ir [1.274 Å], or Cu [1.257−1.287 Å], , are known as are structures for A9 , where the metal is Ru [1.19−1.26 Å] 216 or Cu [1.262−1.266 Å] …”

Section: Spectroscopy and Structurementioning

confidence: 99%

Interactions of Organic Nitroso Compounds with Metals

Lee

¹

,

Chen

²

,

West

³

et al. 2002

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Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

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“…We applied this reaction as a starting point to develop a synthetic route to I-NON (Scheme 1). On the one hand, I-NON, as a representative of the group of nitrosonaphthols, can be useful as a chelator for transition metal complexes and this sequestering can be applied for analytic or extraction purposes [19,20]; on the other hand, the iodine functionality in I-NON, acting as a halogen bond (HaB) donor, might be useful for HaB-based crystal engineering [21][22][23][24][25]. Scheme 1.…”

Section: Synthesis Of 3-iodo-1-nitrosonaphthalen-2-olmentioning

confidence: 99%

Copper(II)-Mediated Iodination of 1-Nitroso-2-naphthol

Efimenko

¹

,

Rozhkov

²

,

Suslonov

³

et al. 2021

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Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

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“…This ligand tautomerizes to the corresponding keto-oxime form ( 2 ), and hence the dissociated anionic ligand (L - ) is best represented as shown in 3 . The anionic ligand is known to coordinate metal ions as a bidentate N,O donor forming a five-membered chelate ring ( 4 ) leaving the oximato oxygen available for further coordination to a second metal ion ( 5 ), and thus it can act as a bridging ligand. Such bridging ability of the oximate function has been successfully utilized by many workers. − Mononuclear complexes of 1-nitroso-2-naphtholate ligand may therefore be expected to serve as building units for the construction of polynuclear assemblies.…”

Section: Introductionmentioning

confidence: 99%

Tris 1-Nitroso-2-naphtholate Complex of Ruthenium(II): An Efficient Building Unit for Polynuclear Complexes

Das

¹

,

Rueda

²

,

Falvello

³

et al. 1999

Get access via publisher Add to dashboard Cite

Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

show abstract

The Crystal and Molecular Structure of the Diacetone Adduct of the Copper(II) Complex of 1-Nitroso-2-naphthol: [Cu(C10H6NO2)2].2(CH3)2CO..

Cited by 20 publications

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Interactions of Organic Nitroso Compounds with Metals

Interactions of Organic Nitroso Compounds with Metals

Copper(II)-Mediated Iodination of 1-Nitroso-2-naphthol

Tris 1-Nitroso-2-naphtholate Complex of Ruthenium(II): An Efficient Building Unit for Polynuclear Complexes

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