The Crystal and Molecular Structure of the Copper(I) Dipropylthiocarbamate Hexamer.

[Cu{SC(O)OiPr}]96: A Giant Self-Assembled Copper(I) Supramolecular Wheel Exhibiting Photoluminescence Tuning and Correlations with Dynamic Solvation and Solventless Synthesis

“…A summary of the MTCO coordination modes observed in ( 2 ) is shown in Figure . The trimetallic-triconnective κ 3 :μ 2 -S, μ-O mode is similar to what has been described in smaller Cu­(I) and Ag­(I) monothiocarbamate complexes, , but the large 36-membered Cu–S ring is by far the largest of its kind reported to date.…”

Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block

“…Six ligands among the 16 use a trimetallic triconnective bridging mode (κ 3 :µ 2 ‐S, µ‐O) to coordinate exclusively to the copper atoms of the extended butterfly motifs. Interestingly, this is the first time that this bridging mode is observed in monothiocarbonate chemistry; however, this kind of bonding was reported previously in monothiocarbamate (mtc) and monothiocarboxylate complexes, for example, [M(SCONR 2 )] 6 (M = Cu and Ag),[12a], [12b] [Ni(SCONR 2 ) 2 ] 6 ,[12c] and [Cu 4 (SC{O}Ph) 4 (PPh 3 ) 3 ] . Similarly, another two sets of monothiocarbonate ligands use a new tetrametallic tetraconnective (κ 4 : µ 3 ‐S, µ‐O) coordination mode to bridge predominantly to the central square pyramidal Cu atoms (Cu8, Cu6, Cu7, Cu10, Cu11) and the extrapolated copper atoms (Cu5, Cu12) in the butterfly structures.…”

Crystallographic evidence for copper-copper bonding at 2.8 Ang. Crystal and molecular structure of tetrakis(tetraphenylphosphonium) hexakis(1,2-dithiosquarato)octacuprate(I)

“…This latter distance is certainly nonbonded, but there are numerous other copper(I) cluster compounds with Cu-Cu distances which are intermediate between these two extremes [3][4][6][7][8][9][10] (1) J. M. Guss, R. Mason, I. Sotofte, G. van Koten, and J. G. Noltes, J. Chem. Soc., Chem.…”