“…The coating experiences only a certain degree of swelling when the NaCl solution permeates at the beginning, and the internal structure is damaged less, which is similar to the phenomenon observed in the experiments. 3,14 The indentation force after permeation of Gr/EP coatings is lower than that of pure EP coatings due to the deformation and movement of Gr during the permeation process, which prevents the enhancement effect. Comparing Figure 6B,E, after the permeation of the Gr/EP coating, the Gr moves to the left by a certain distance…”
Section: Nanoindentation Analysis After Coating Permeationmentioning
confidence: 99%
“…5,6 Graphene (Gr) 7,8 and its derivative graphene oxide (GO) 9,10 have been used to enhance epoxy coatings due to their unique mechanical and physical properties. 11 Previously, researchers measured the electrochemical impedance in salt spray experiments 12,13 and accelerated corrosion experiments 14 to investigate the corrosion resistance of epoxy composite coatings. 15,16 The enhancement of corrosion resistance of epoxy coatings by twodimensional materials such as Gr and GO was investigated at a macroscopic level to summarize the antipermeation mechanism of polymer composite coatings.…”
The permeation of marine water can lead to severe degradation of the protective properties of polymer composite coatings. At present, experimental studies on the anticorrosive and mechanical properties of polymer composite coatings are relatively mature, but the impermeability and mechanical property changes of the coating during the permeation process are challenging tasks to be studied only by experiments. In this paper, molecular dynamics (MD) models of composite coatings consisting of pure epoxy resin (EP), graphene/epoxy resin (Gr/EP), and graphene oxide/epoxy resin (GO/EP) were constructed respectively. MD simulations were performed to reveal the impermeability and mechanical property changes of composite coatings from an atomic perspective. The results show that GO has strong interfacial interaction with EP and the best effect to enhance the impermeability and mechanical properties of epoxy coatings. NaCl solutions can damage the coating microstructure and occupy the Gr and GO surfaces, causing them to no longer have an enhancing effect. The study of GO/EP coatings with different permeation degrees shows that the mechanical properties of the coating decrease as the penetration degree increases.
“…The coating experiences only a certain degree of swelling when the NaCl solution permeates at the beginning, and the internal structure is damaged less, which is similar to the phenomenon observed in the experiments. 3,14 The indentation force after permeation of Gr/EP coatings is lower than that of pure EP coatings due to the deformation and movement of Gr during the permeation process, which prevents the enhancement effect. Comparing Figure 6B,E, after the permeation of the Gr/EP coating, the Gr moves to the left by a certain distance…”
Section: Nanoindentation Analysis After Coating Permeationmentioning
confidence: 99%
“…5,6 Graphene (Gr) 7,8 and its derivative graphene oxide (GO) 9,10 have been used to enhance epoxy coatings due to their unique mechanical and physical properties. 11 Previously, researchers measured the electrochemical impedance in salt spray experiments 12,13 and accelerated corrosion experiments 14 to investigate the corrosion resistance of epoxy composite coatings. 15,16 The enhancement of corrosion resistance of epoxy coatings by twodimensional materials such as Gr and GO was investigated at a macroscopic level to summarize the antipermeation mechanism of polymer composite coatings.…”
The permeation of marine water can lead to severe degradation of the protective properties of polymer composite coatings. At present, experimental studies on the anticorrosive and mechanical properties of polymer composite coatings are relatively mature, but the impermeability and mechanical property changes of the coating during the permeation process are challenging tasks to be studied only by experiments. In this paper, molecular dynamics (MD) models of composite coatings consisting of pure epoxy resin (EP), graphene/epoxy resin (Gr/EP), and graphene oxide/epoxy resin (GO/EP) were constructed respectively. MD simulations were performed to reveal the impermeability and mechanical property changes of composite coatings from an atomic perspective. The results show that GO has strong interfacial interaction with EP and the best effect to enhance the impermeability and mechanical properties of epoxy coatings. NaCl solutions can damage the coating microstructure and occupy the Gr and GO surfaces, causing them to no longer have an enhancing effect. The study of GO/EP coatings with different permeation degrees shows that the mechanical properties of the coating decrease as the penetration degree increases.
“…Nowadays, coating protection performance is usually evaluated according to the following coating characteristics: The physical and chemical changes, such as the gloss loss (Guseva et al , 2003; Evans, 2012), the color change (Lee and Chang, 2016), the emergence of rust (Kim and Itoh, 2007), the adhesion failure (Zhang et al , 2020a; Zhang et al , 2020b; Meng et al , 2017) and the occurrence of blistering (Latif et al , 2017; Chuang and Nguyen, 1997; Bethencourt et al , 2004; Xu et al , 2021; Zheng et al , 2021). The electrochemical resistance reduction, such as the decreased coating resistance (Cmaitland and Mayne, 1962; Deflotian et al , 2008; Yong et al , 2021) and the reduced low frequency modulus (Bierwagen et al , 2001; Shreeoathi et al , 2011; Su et al , 2015).…”
Section: Introductionmentioning
confidence: 99%
“…The physical and chemical changes, such as the gloss loss (Guseva et al , 2003; Evans, 2012), the color change (Lee and Chang, 2016), the emergence of rust (Kim and Itoh, 2007), the adhesion failure (Zhang et al , 2020a; Zhang et al , 2020b; Meng et al , 2017) and the occurrence of blistering (Latif et al , 2017; Chuang and Nguyen, 1997; Bethencourt et al , 2004; Xu et al , 2021; Zheng et al , 2021).…”
Section: Introductionmentioning
confidence: 99%
“…Particularly, electrochemical methods (Rodríguez et al , 2004), e.g. the AC–DC–AC tests (Hollaender, 1997; Xu et al , 2021; Zheng et al , 2021), can significantly speed up the corrosion and delamination of organic coatings at the coating/substrate interface. However, all these methods more or less change the coating deterioration mechanism while they are speeding up the coating degradation process.…”
Purpose
This study aims to provide a model to predict the service life of a thick organic coating.
Design/methodology/approach
A series of thin coating films are rapidly tested under the same exposure condition as the thick coating in its service condition by means of electrochemical impedance spectroscopy, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction.
Findings
The validity of the model is successfully verified. The long-term protectiveness or service life of a thick organic coating can be rapidly predicted.
Originality/value
The prediction model does not require long-term experiments or any test that may alter the degradation mechanism of the thick coating.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.