People who work in highway toll station is suffering serve air pollution, due to where vehicles are crowded. So it is important to study the air pollution in highway toll stations. In this study, two toll stations in Dalian were chosen to measure the CO, PM 10 , NO 2 and total hydrocarbon (THC) inside and outside the toll stations. It was found that inside concentrations of PM 10 exceed China Indoor Air Quality Standard (GB/T1883-2002) and outside concentrations of CO, PM 10 and NO 2 exceed China Environment Air Quality Standard (GB3095-2012). The factors affecting the air pollution at toll stations were the traffic volume, source of external pollution, including industrial soot pollution and coal-fire nearby, and diffusion. Methods Measurement Sites. In our study, two toll stations were chosen, one of which was Toll Station of Dalian (TSD) and the other one was a Toll Station of Zhoushuizi Airport (TSZA). TSD was far from the urban area, with spacious terrain and without obvious pollution source nearby. There were 22 toll gates with a daily traffic flow capacity of around 17000 vehicles. TSZA was closer to the urban area than TSD, which was within an industrial district. There were ten toll gates with a daily traffic flow capacity of around 8000 vehicles. Our measurement was carried out in December, 2012. During the measurement, the ambient temperature was 2-5 °C and the northerly wind was 3rd-4th level.