“…Cluster analysis grouped the samples into four main clusters and the best results were obtained using Raman spectroscopic analysis (Mao and Xu, 2006). A combination of FT-IR with PCA, SIMCA and LDA was applied to the classification of Phyllanthus niruri according to geographical location or variety, where the best discriminatory approach was obtained by LDA (Dharmaraj et al, 2006). As mentioned previously, PLS has been used in many studies to predict the active constituents, the content of caffeine and total polyphenols in tea, and SIMCA has been used to identify tea varieties from different origins (Chen et al, 2006b).…”