The chemical structure of triblock copolymers and the adsorption capacity of perfluorocarbon—core nanoparticles stabilized by them

Zhalimov, V. K.; Sklifas, A. N.; Kaptsov, Vladimir; Penkov, Nikita V.; Temnov, A. A.; Kukushkin, N. I.

doi:10.1007/s00396-017-4245-z

Cited by 3 publications

(1 citation statement)

References 15 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Studies have also reported on various PFD properties: vapor pressure [90], phase data (LLE with hydrocarbon binary [91], ternary, etc. systems [92]); nucleation rate of gas hydrates [93,94], extraction [95], and gas solubility (liquid-gas partition-coefficients of halothane and isoflurane [96], N 2 , N 2 O, NH 3 , O 2 , and CO 2 [97][98][99][100]); density and viscosity [90,[101][102][103][104]; surface properties (surface tension [104,105], interfacial tension against water [106], influence of pluronic F-68 dissolved in the aqueous phase [107], and wetting dynamics [108]); aqueous emulsions (preparation and physicochemical properties [109,110], effect of flocculation on particle enlargement [111]); adsorption properties [112] and aerodynamic diameter [113]; molecular structure and spectral properties (electron-diffraction of the gas phase structure [114], infrared spectra and radiative efficiency [115], NMR spectrum [63,116], conformation [117][118][119][120], and isomerization [121][122][123][124]); chemical and biological inertness of PFD [125][126][127]. Mos...…”

Section: Introductionmentioning

confidence: 99%

Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data

Lupachev,

Voshkin,

Kisel’

et al. 2023

Processes

View full text Add to dashboard Cite

New physicochemical data for trans-perfluorodecalin (trans-PDF) and cis-perfluorodecalin (cis-PFD) are presented. Based on the differential scanning calorimetry, the temperature and heat of the solid−liquid phase transition are determined. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties («zero» shear viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Gas chromatography–mass spectrometry data and FTIR, 13C NMR, and 19F NMR spectra are provided. The dependencies are given for the perfluoro(butylcyclohexane) (BCH)–trans-PFD, BCH–cis-PFD, and trans-PFD–cis-PFD binary systems and BCH–trans-PFD–cis-PFD ternary system: refractive index and density (liquid molar volume and excess molar volume) of composition and temperature. The dependences of the excess molar volume on the composition and temperature of the mixtures are correlated with Redlich-Kister and Kohler equations.

show abstract