We have observed the 1s2s 1 S 0-1s2p 3 P 0 transition in 14 N 51 using Doppler-tuned fast-beam laser spectroscopy. This transition, absolutely forbidden for atoms with zero nuclear spin, occurs due to mixing of states of different J by the hyperfine interaction. By measuring the difference between the 2 1 S 0-2 3 P 1,F and 2 1 S 0-2 3 P 0 transition energies, we have obtained a value for the 1s2p 3 P 1-3 P 0 fine-structure splitting in N 51. Our result will test quantum-electrodynamic corrections to recent high precision calculations [Z.-C. Yan and G. W. F. Drake, Phys. Rev. Lett. 74, 4791 (1995)]. [S0031-9007(96)00403-6]