Using Doppler-tuned fast-beam laser spectroscopy with co-and counterpropagating beams we have measured the three hyperfine components of the 1s2p 3 P 2 -3 P 1 fine structure interval in 19 F 71 . Our result for the centroid is 957.6679͑10͒ cm 21 . Allowing for the hyperfine interaction the "pure" fine structure interval is determined to be 957.8730͑12͒ cm 21 . This result tests O͑a 7 m e c 2 ͒ quantum electrodynamic corrections to high precision calculations which will be used to obtain a new value for the fine structure constant from the fine structure of helium. [S0031-9007 (99)09157-7] PACS numbers: 32.10.Fn, 06.20.JrThe fine structure constant, a, is the fundamental constant which expresses the elementary charge in dimensionless form and hence plays a crucial role in unifying an enormous range of physical phenomena [1]. There is now a program to obtain a new value for a from comparison of theory and experiment for the 1s2p 3 P J2J 0 fine structure of atomic helium. Drake and co-workers, using matrix elements of operators derived from the Bethe-Salpeter equation, evaluated with high-precision nonrelativistic wave functions, aim to complete calculations to order a 5 a.u. (or a 7 m e c 2 ) [2-4]. Independent calculations of the effective operators are also being carried out by Pachucki [5]. This is expected to result in a theoretical value for the larger, approximately 29.6 GHz, J 0 1 interval in helium to better than 61 kHz. Combined with measurements aimed at exceeding this precision [6-9], this should yield a value for a at the 16 ppb (parts per 10 9 ) level. This would be of interest for comparison with the result obtained from QED theory and experiment for the electron magnetic moment, and with results obtained from the various other phenomena reviewed in Ref. [1].Compared to other methods dependent on QED theory for obtaining a, helium fine structure has an advantage in that the theory, in particular, the evaluation of the complex higher-order relativistic and QED corrections, FIG. 1. Schematic of the experimental arrangement. G is a diffraction grating, W is a window, L is a lens, M1, M2 are mirrors, EM1, EM2 are electromagnets, PM is a permanent magnet, and PC is a proportional counter.can be independently tested. This is because there are two 2 3 P fine structure intervals and because the same methods used for helium can be used to calculate fine structure in moderate Z heliumlike ions where the relative magnitudes of these higher-order terms are larger. Hence fine structure measurements in moderate Z heliumlike ions [10-15], even though less precise than measurements in helium, can provide sensitive tests of the theory. Here we report a measurement of the three hyperfine components of the 19 F 71 1s2p 3 P 2 -3 P 1 fine structure interval, obtained by directly inducing the M1 transitions using a CO 2 laser, in a fast, foil stripped fluorine ion beam. A novel Doppler shift cancellation technique was used which measures products of the transition energies in pairs. Our result, with a precision of 61 ppm ...