1962
DOI: 10.1016/0006-3002(62)90406-7
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The biosynthesis of the “pyrethrins”

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1969
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Cited by 29 publications
(5 citation statements)
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“…6 Tlc on silica gel plate (Merk GF254, 0.5 mm) with benzene-ether mixture (30:1) gave a yellow spot of the hydrazone, which was scraped, eluted with methanol, and measured spectrophotometrically at 382 m i (log e=4.46) with Shimadzu Spectrophotometer QV-50.…”
Section: Methodsmentioning
confidence: 99%
“…6 Tlc on silica gel plate (Merk GF254, 0.5 mm) with benzene-ether mixture (30:1) gave a yellow spot of the hydrazone, which was scraped, eluted with methanol, and measured spectrophotometrically at 382 m i (log e=4.46) with Shimadzu Spectrophotometer QV-50.…”
Section: Methodsmentioning
confidence: 99%
“…A Spectrophotometer method has been used to measure the concentration of Pyrethrins in flowers. (Crowley, 1962). The economics of the crop were calculated under different treatments.…”
Section: Methodsmentioning
confidence: 99%
“…Although there has been little experimental verification of any biosynthetic pathway, the available data2 coupled with biogenetic analogies to presqualene alcohol and the known chemical3 interconversions of the chrysanthemyl carbon skeleton with other non-headto-tail monoterpene carbon skeletons have led to a unified hypothesis for the biosynthesis of these compounds.4 This hypothesis requires (17?,37? )-chrysanthemyl pyrophosphate (1, R = pyrophosphate) as a key intermediate in the formation of the chrysanthemyl (2), artemesyl (3), and santolinyl (4) types of irregular monoterpenes. With the ubiquitous occurrence of phosphatases in plants, it might be expected that any plants producing 1 (R = pyrophosphate) would also have the corresponding alcohol, (17?,37?…”
Section: References and Notesmentioning
confidence: 99%