Measurements of electrical conduction in the bulk of chemical vapor deposited (CVD) SiO.2 and phosphosilicate glass (PSG) passivation layers typically used for over-me~al IC protection are reported. Moisture uptake increases the bulk conductivity, and the moisture effects depend on phosphorus content. The bulk current thermal activation energy of CVD SiO.~ (0.6 eV) is constant with varying moisture exposure. Before moisture exposure, phosphorus-containing glass has an activation energy of 0.8 eV, and it decreases with moisture exposure. Surface conductivity is also reported as a function of relative humidity. Conductivity values are related to IC leakage currents, and it is suggested that bulk currents in PSG should not contribute to aluminum corrosion in the absence of defects, such as cracks or pinholes.SiO~ and phosphosilicate glass (PSG) are important materials in silicon device passivation (1). Thin layers of PSG (hundreds of angstroms) have been described as useful for Na-gettering under gate metal of MOS devices (2-4). Thin layers must be used to avoid instabilities due to PSG polarization (3, 5-7). For overmetal passivation of IC's, thicker layers (about 104fl,) can be used (since polarization of the PSG is unimportant in this geometry). Generally, over-metal layers are deposited by chemical vapor deposition (CVD) (8-11 ). The phosphorus addition lowers intrinsic stress over aluminum metal and provides Na-gettering capability (12), which is particularly useful in plastic packaged devices. In addition, the passivating glass over metal provides important scratch protection during the device production process (13), and serves as insulating protection against loose conducting particles in hermetic packages (14).The bulk and surface electrical properties of CVD passivation over metal are important in understanding Na-gettering (4, 15) device leakage as affected by lateral charge spreading (16-21), metal corrosion (22-25), and moisture effects (24,25).In this report, measurements of bulk electrical conductivity as a function of water uptake and temperature, and surface conductivity as a function of relative humidity (RH) are reported for CVD SiO2 and CVD PSG. The data are used in estimating electrical and moisture effects typical for IC's.
Sample PreparationThe glass layers were deposited on degenerate ntype (0.01 ohm-cm) silicon wafers at 450~ at a growth rate of about 1000 A/min to a total thickness of 1 ~m, using a reactor described by Kern (11,26). Phosphorus concentrations, determined by etch rate analysis, are 0, 4.8, and 8.5 weight per cent (w/o) P in the glass. No postdeposition heat-treatments were applied. * Electrochemical Society Active Member.