Silver doped glass powders have been obtained starting from vitellinate/nAg and montmorillonite/nAg. These powders have shown a high biocide activity against the three different types of microorganisms studied: Escherichia coli (gram‐negative bacteria), Micrococcus luteus (gram‐positive‐bacteria), and Issatchenkia orientalis (yeast). It was found that these glasses keep constant the silver concentration even below the cytotoxic limit. Therefore we interpret that silver doped glasses play the role of dosing devices.