2020
DOI: 10.1016/j.ijhydene.2019.06.132
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The advanced photocatalytic performance of V doped CuWO4 for water splitting to produce hydrogen

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Cited by 27 publications
(5 citation statements)
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“…The specific type of Cu species cannot be identified by the SEM analysis. However, the chemical valence of the Cu element is +2, which was determined by the characteristic peaks of Cu 2p 1/2 and 2p 3/2 at 955.0 and 935.0 eV, respectively (see Figure b). ,, Hence, the Cu species is CuO. Figure c–e shows no change in the high-resolution Sr 3d, Ce 3d, and W 4f between the 3%-CuO/Sr 0.76 Ce 0.16 WO 4 and Sr 0.76 Ce 0.16 WO 4 samples.…”
Section: Resultsmentioning
confidence: 92%
“…The specific type of Cu species cannot be identified by the SEM analysis. However, the chemical valence of the Cu element is +2, which was determined by the characteristic peaks of Cu 2p 1/2 and 2p 3/2 at 955.0 and 935.0 eV, respectively (see Figure b). ,, Hence, the Cu species is CuO. Figure c–e shows no change in the high-resolution Sr 3d, Ce 3d, and W 4f between the 3%-CuO/Sr 0.76 Ce 0.16 WO 4 and Sr 0.76 Ce 0.16 WO 4 samples.…”
Section: Resultsmentioning
confidence: 92%
“…Figure 1b represents the optical bandgap energies of 2.90 eV, which is obtained using the Tauc plot for CuWO 4 . The obtained value of the bandgap, has coherence compared to other investigations that consider CuWO 4 as a photocatalyst of interest with a bandgap of 2.25 eV to 2.4 eV [44][45][46]. Hence, CuWO 4 has a narrow bandgap because of this small bandgap energy, it can resist photocorrosion [47,48] in an aqueous solution at a neutral pH.…”
Section: Sample Preparationmentioning
confidence: 80%
“…S5b, ESI †). These phenomena are evidence for the successful integration of P to CuO/Cu 2 S. Because the ionic radius of P ions (0.044 nm) is smaller than those of the O ions (0.135 nm) and S ions (0.184 nm), 28 the partial replacement of O and S with P leads to a lattice shrinkage and thereby causing a shift in the direction of higher angles of CuO and Cu 2 S diffraction peaks, 34 which is in accordance with the HR-TEM observations. According to the XRD results, the crystal structures of CuO and Cu 2 S are determined and illustrated in Fig.…”
Section: Resultsmentioning
confidence: 99%