Tetrathiafulvalene End-Functionalized Poly(<i>N</i>-isopropylacrylamide): A New Class of Amphiphilic Polymer for the Creation of Multistimuli Responsive Micelles

Bigot, J. A.; Charleux, Bernadette; Cooke, Graeme; Delattre, François; Fournier, David; Lyskawa, Joël; Sambe, Léna; Stoffelbach, François; Woisel, Patrice

doi:10.1021/ja1027452

Cited by 125 publications

(126 citation statements)

References 71 publications

(35 reference statements)

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“…Woisel, Cook et al have demonstrated the potential of specific host-guest interactions to control micelle formation of a tetrathiafulvalene (TTF) end-functionalized poly(N-isopropylacrylamide) PNIPAAm amphiphilic polymer [63]. Using Nile red as a molecular fluorescent probe, the formation of micelles containing a TTF core was confirmed by fluorescence studies.…”

Section: Modulating Polymeric Architectures By Supramolecular Interacmentioning

confidence: 99%

Supramolecular control over thermoresponsive polymers

2016

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Thermoresponsive polymers facilitate the development of a wide range of applications in multiple areas spanning from construction or water management to lab-on-a-chip technologies and biomedical sciences. The combination of thermoresponsive polymers with supramolecular chemistry, inspired by the molecular mechanisms behind natural systems, is resulting in adaptive and smart materials with unprecedented properties. This work reviews the past advances on the combination of this young field of research with polymer chemistry that is enabling a high level of control on polymer architecture and stimuli-responsiveness in solution. We will discuss how such polymer systems are able to store thermal information, respond to multiple stimuli in a reversible manner, or adapt their morphology on demand, all powered by the synergy between polymer chemistry and supramolecular chemistry

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Section: Modulating Polymeric Architectures By Supramolecular Interacmentioning

confidence: 99%

Supramolecular control over thermoresponsive polymers

2016

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“…Nowadays, many amphiphilic polymer-based micelles have been developed as a result of their more versatile structure and function compared to that of lipid. 119,120 Liposomes are capable of carrying both hydrophobic and hydrophilic drugs at the same time. The hydrophobic drugs can be integrated into the fatty acid shell while the hydrophilic drugs can be loaded into the aqueous core.…”

Section: Organic Nanoscale Materials Employed For Pharmaceutical Devementioning

confidence: 99%

Biosafe Nanoscale Pharmaceutical Adjuvant Materials

Jin¹,

Li²,

Wang³

et al. 2014

j biomed nanotechnol

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Thanks to developments in the field of nanotechnology over the past decades, more and more biosafe nanoscale materials have become available for use as pharmaceutical adjuvants in medical research. Nanomaterials possess unique properties which could be employed to develop drug carriers with longer circulation time, higher loading capacity, better stability in physiological conditions, controlled drug release, and targeted drug delivery. In this review article, we will review recent progress in the application of representative organic, inorganic and hybrid biosafe nanoscale materials in pharmaceutical research, especially focusing on nanomaterial-based novel drug delivery systems. In addition, we briefly discuss the advantages and notable functions that make these nanomaterials suitable for the design of new medicines; the biosafety of each material discussed in this article is also highlighted to provide a comprehensive understanding of their adjuvant attributes.

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“…For the study of micellization, the amphiphilic, linear poly(N-isopropylacrylamide) (PNIPAM) derivative 47 functionalized by TTF was used in aqueous solution. 38,39 The temperature-induced micellization was monitored by fluorescence spectroscopy, dynamic light scattering (DLS) and differential scanning calorimetry. The amphiphilic polymers of the type 47 can self-assemble in water to give multistimuli responsive polymeric micelles.…”

Section: Scheme 13mentioning

confidence: 99%

Donor-acceptor rotaxanes with tetracationic cyclophane ring

Deska¹,

Nowik-Zając²,

Śliwa³

2013

Arkivoc

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In the first part of the review the selected examples of title rotaxanes are shown, among them those containing thiophene and acridane units, as well as those of the dendrimeric structure. In the second part the rotaxanes with electrostatic or steric barriers, incorporated for increase of lifetime of their metastable state, are presented. The third part of the review deals with rotaxanes investigated in the aspect of their secondary structure, and in the fourth part rotaxanes containing a modified tetracationic cyclophane ring are described.

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Tetrathiafulvalene End-Functionalized Poly(N-isopropylacrylamide): A New Class of Amphiphilic Polymer for the Creation of Multistimuli Responsive Micelles

Cited by 125 publications

References 71 publications

Supramolecular control over thermoresponsive polymers

Supramolecular control over thermoresponsive polymers

Biosafe Nanoscale Pharmaceutical Adjuvant Materials

Donor-acceptor rotaxanes with tetracationic cyclophane ring

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