Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate

Abstract

Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.007 Å R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3For details of how these key indicators were automatically derived from the article, see

Di-μ-thiocyanato-bis[bis(tri-p-tolylphosphine)silver(I)] acetonitrile disolvate

“…For related silver(I) thiocyanate complexes, see: Bowmaker et al (1997); Effendy et al (2005). For related silver(I) tri-p-tolylphosphine complexes, see: ; Meijboom ( , 2007; ; Venter et al (2006)7. For related literature, see: Allen (2002).…”

Iodotris(tri-p-tolylphosphine)silver(I)

“…As part of our investigation of the coordination of tri-ptolylphosphine to silver(I) (Meijboom, 2006;Venter et al, 2006), we report here the solid-state structure of the title compound, [Ag{P(4-MeC 6 H 4 ) 3 } 3 I], (I).…”

Concomitant polymorphic behavior of di-μ-thiocyanato-κ2 N:S;κ2 S:N-bis[bis(tri-p-fluorophenylphosphine-κP)silver(I)]

“…This can easily be studied in cases where one of the polymorphs has more than one molecule in the asymmetric unit (Hansson et al, 2008). Previous studies were performed on the roles played by different properties of ligands during the crystallization of simple silver(I) salts with Group 15 donor ligands, with the initial focus on tri-p-tolylphosphine complexes Meijboom, 2006Meijboom, , 2007Venter et al, 2006; which allowed for comparison with the isosteric triphenylphosphine complexes.…”