“…Nanostructured transition metal oxides (MO, where M is Fe, Co, Ni and Cu) are considered as promising candidates for numerous applications, such as, lithium ion batteries 1 , 2 , supercapacitor 3 – 5 , gas sensor 6 , 7 , electrocatalyst 8 , 9 and so on. In order to meet different requirements of applications, MO nanostructures with various morphologies including nanowires 10 , nanotubes 11 , nanorods 12 , nanoflakes 13 and hollow nanospheres 14 , have been developed. Among all of them, hollow nanostructure has attracted intensive research interests owing to its special structural features including high surface area, high surface reaction activity and fast diffusion ability, which are beneficial to the improvement of the catalytic performance, gas sensing, as well as the battery properties 15 .…”