Acetonitrile and water are molecules
detected not only in space
but also in planetary atmospheres. On the Earth, the nitrile compound
is emitted from biomass burning and can be found up to the stratosphere.
Trapped in water ice cores, they may be exposed to energetic particles,
photons and secondary electrons, and contribute to the formation of
complex organic molecules. Here, we show that methanol is the main
product from the effective reaction of low-energy (<15 eV) electrons
with acetonitrile–water films deposited on a substrate maintained
at 85 K. In this process, each of the molecules is decomposed by the
colliding electrons, producing respectively methyl and hydroxyl radicals,
which further recombine to form methanol, as supported by density
functional theory (DFT) calculations. In addition, we also report
production of a small amount of glycolonitrile, a key precursor of
adenine. This information contributes to a better comprehension and
description of chemistry of icy grains.