Temperature-influenced M2L and M2L2 molecular metal phosphonates and diversity of ligand conformation

Sung, Hui-Ling; Weng, Wen-Pin; Lin, Shen-Fu; Yang, Hsin-Chou; Wu, Jing‐Yun

doi:10.1016/j.ica.2020.119998

Cited by 5 publications

(1 citation statement)

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“…In recent, we have made our efforts on the construction of two-and three-component metal phosphonates involving polymeric frameworks and discrete molecular structures. [59,60,[70][71][72][73] With great significance in environmental monitoring, we are interesting in novel metal phosphonates based luminescence sensor materials for stimuli-responsive multifunctional detection. [56,57] Subsequent to our efforts on metal phosphonates, we look forward to lanthanide phosphonate complexes for the exploration of new color-tunable light-emitting materials and excellent multidisciplinary sensor materials.…”

Section: Introductionmentioning

confidence: 99%

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection

Tsai

et al. 2023

Chemistry A European J

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Molecular lanthanide phosphonates [Ln 2 (H 3 tpmm) 2 (H 2 O) 6 ] • xH 2 O (Ln=Eu, EuP; Ln=Tb, TbP) were synthesized. Single-crystal X-ray diffraction confirmed that EuP has a sandwich-like dinuclear structure, in which the Eu(III) center adopts a {EuO 8 } distorted dodecahedral geometry. XRPD patterns prove that TbP and EuP are isomorphous and isostructural.EuP and TbP are highly thermally stable approaching 450 °C and exhibit red-and green-light emissions from the characteristic 4 f-4 f transition of the Eu 3 + and Tb 3 + , respectively. Interestingly, luminescence modulation is achieved for the chemically mixed Eu/Tb phosphonate analogues, c-Eu x Tb 2-x P (x = 1.5, 1, 0.5), and physically mixed Eu/Tb phosphonate materials, p-yEuP : zTbP (y : z = 3 : 1, 1 : 1, 1 : 3), with varying the excitation wavelength. Of particular note, near-white-light emission is also achieved for c-EuTbP, p-EuP : TbP, and p-EuP : 3TbP when excited at 365 nm. Therefore, these dinuclear molecular lanthanide phosphonates emitting excitation wavelength and Eu 3 + : Tb 3 + ratio dependent luminescence might be potential candidates for color-tunable luminescence materials and white-light-emitting materials. On the other hand, the bright green-light emission makes TbP to be an excellent reusable luminescence sensor for selective detection of Fe 3 + with Stern-Volmer quenching constant (K SV ) of 9.66 × 10 3 M À 1 and detection limit (DL) of 0.42 μM through absorption competition caused luminescence quenching effect.

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Section: Introductionmentioning

confidence: 99%

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection

Tsai

et al. 2023

Chemistry A European J

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Significance and properties of the complex formation of phosphate and polyphosphate groups in particles present in living cells

Jastrząb

Nowak

Zabiszak

et al. 2021

Coordination Chemistry Reviews

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A three-component copper phosphonate complex as a sensor platform for sensitive Cd2+ and Zn2+ ion detection in water via fluorescence enhancement

Tsai

Sung

et al. 2021

Journal of Solid State Chemistry

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Temperature-influenced M2L and M2L2 molecular metal phosphonates and diversity of ligand conformation

Cited by 5 publications

References 40 publications

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection

Significance and properties of the complex formation of phosphate and polyphosphate groups in particles present in living cells

A three-component copper phosphonate complex as a sensor platform for sensitive Cd2+ and Zn2+ ion detection in water via fluorescence enhancement

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Temperature-influenced M2L and M2L2 molecular metal phosphonates and diversity of ligand conformation

Cited by 5 publications

References 40 publications

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe3+ Detection

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe3+ Detection

Significance and properties of the complex formation of phosphate and polyphosphate groups in particles present in living cells

A three-component copper phosphonate complex as a sensor platform for sensitive Cd2+ and Zn2+ ion detection in water via fluorescence enhancement

Contact Info

Product

Resources

About

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection

Excitation‐Wavelength‐Dependent Luminescence of Chemically and Physically Mixed Europium and Terbium Phosphonates: Color‐Tunable Luminescence, Near‐White‐Light Emission, and Selective Fe³⁺ Detection