2009
DOI: 10.1002/ange.200804599
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Telomerisation – Fortschritte und Anwendungen einer vielseitigen Reaktion

Abstract: Wandelbar wie ein Chamäleon: Die übergangsmetallkatalysierte Telomerisation von 1,3‐Dienen mit verschiedenen Nucleophilen führt zur zahlreichen Produkten, die sowohl in Kosmetika und Pharmaka als auch in Polymeren und Duftstoffen Anwendung finden. Der Aufsatz gibt einen Überblick über diese vielseitige Reaktion mit Bezug auf die aktuelle Forschung und industrielle Anwendungen.magnified imageDurch übergangsmetallkatalysierte Telomerisation von 1,3‐Dienen mit verschiedenen Nucleophilen lassen sich zahlreiche fun… Show more

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Cited by 36 publications
(13 citation statements)
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“…In the field of homogeneous catalysis, the term telomerization refers to a metal‐catalyzed dimerization of 1,3‐dienes with the addition of a nucleophile, which in almost all cases is H‐acidic. Typical side reactions are the palladium‐catalyzed linear dimerization of 1,3‐butadiene to 1,3,7‐octatrienes and the non‐catalyzed Diels‐Alder dimerization to 4‐vinylcyclohexene (Scheme ) ,…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…In the field of homogeneous catalysis, the term telomerization refers to a metal‐catalyzed dimerization of 1,3‐dienes with the addition of a nucleophile, which in almost all cases is H‐acidic. Typical side reactions are the palladium‐catalyzed linear dimerization of 1,3‐butadiene to 1,3,7‐octatrienes and the non‐catalyzed Diels‐Alder dimerization to 4‐vinylcyclohexene (Scheme ) ,…”
Section: Introductionmentioning
confidence: 99%
“…Behr et al published the latest and most comprehensive review about the telomerization in 2009 ,. Building on this, the present review focuses on gathering, categorizing and discussing the research over the past ten years.…”
Section: Introductionmentioning
confidence: 99%
“…The telomerisation of 1,3dienes with nucleophiles has been studied extensively in both academic and industrial laboratories. [1] The telomerisation of buta-1,3-diene (Bd) with methanol is the key step of the commercial route developed by the Dow Chemical Company (Dow) to produce oct-1-ene (Scheme 1). [2] The process came on stream in Tarragona in 2007 and is based on the use of a crude C4 cut (containing 50 wt % of buta-1,3-diene).…”
Section: Introductionmentioning
confidence: 99%
“…[34] Because of the typical product pattern of 1,3-dienes the hydroamination leads predominantly to the 1,4-adducts 1 and 2. The desired products are the amines (2), resulting from an amine attack on the tail Scheme 2.…”
Section: Hydroamination Under Single Phase Conditionsmentioning
confidence: 99%