1999
DOI: 10.1021/cr970413r
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Tandem Reaction Sequences under Hydroformylation Conditions:  New Synthetic Applications of Transition Metal Catalysis

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Cited by 542 publications
(242 citation statements)
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“…The six methallyl fragments are used for dendrimer synthesis by hydroaminomethylation [2], am ulti step reaction with hydroformylation as the initial step. The hydroformylation reaction, the most important homogeneously catalyzedr eaction, produces amixture of linear and branched aldehydes from olefins, carbon monoxide and hydrogen [3].…”
Section: Discussionmentioning
confidence: 99%
“…The six methallyl fragments are used for dendrimer synthesis by hydroaminomethylation [2], am ulti step reaction with hydroformylation as the initial step. The hydroformylation reaction, the most important homogeneously catalyzedr eaction, produces amixture of linear and branched aldehydes from olefins, carbon monoxide and hydrogen [3].…”
Section: Discussionmentioning
confidence: 99%
“…9 Ennek a legnagyobb része az aldol dimerizációval 2-etil-hexanollá alakítható butiraldehid, mely a mûanyaglágyítóként népszerû dioktil-ftalát egyik alapanyaga. Az aldehidek önmagában is értékes termékek lehetnek, azonban (gyakran tandem, vagy dominó reakcióban 10 ) továbbalakíthatók alkoholokká, karbonsavakká, vagy aminokká. A királis aldehideket eredményezõ aszimmetrikus hidroformilezés az enantiomerikusan tiszta termékek iránt egyre nagyobb igénnyel fellépõ gyógyszer-és növényvédõszer ipar számára válik jelentõssé.…”
Section: áBra a Hidroformilezési Reakció Etilén (A) Aromás Olefinekunclassified
“…Carbonylative hydroaminomethylation (hydroformylation-reductive amination) [109][110][111][112][113][114][115] has only been reported for mono-olefin reactants, as hydroformylation of dienes and allenes suffers from poor regioselectivity and "over-hydroformylation" to form dialdehyde products. In contrast, 2-propanol-mediated reductive couplings of allenes or dienes with formaldimines (generated in situ from saturated 1,3,5-triazines) are efficient and selective processes.…”
Section: Hydroaminoalkylationmentioning
confidence: 99%