Synthesis through 3D printing: formation of 3D coordination polymers

Halevi, Oded; Chen, Jingwei; Thangavel, Gurunathan; Morris, Samuel A.; Uliel, Tal Ben; Tischler, Yaakov R.; Lee, Pooi See; Magdassi, Shlomo

doi:10.1039/d0ra01887b

Cited by 18 publications

(19 citation statements)

References 41 publications

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“…b , c , d , e Pictures of different architectures of the 3- D -printed polyNiComplex catalytic material by Oded et al . Adapted with permission from reference [ 98 ]. Copyright [2020], [Royal Society of Chemistry] …”

Section: Role Of 3-d Printing In Chemistry and Associated Fieldsmentioning

confidence: 99%

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Current and future trends of additive manufacturing for chemistry applications: a review

Alimi

Meijboom

2021

J Mater Sci

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Graphical abstract Three-dimensional (3- D ) printing, also known as additive manufacturing, refers to a method used to generate a physical object by joining materials in a layer-by-layer process from a three-dimensional virtual model. 3- D printing technology has been traditionally employed in rapid prototyping, engineering, and industrial design. More recently, new applications continue to emerge; this is because of its exceptional advantage and flexibility over the traditional manufacturing process. Unlike other conventional manufacturing methods, which are fundamentally subtractive, 3 -D printing is additive and, therefore, produces less waste. This review comprehensively summarises the application of additive manufacturing technologies in chemistry, chemical synthesis, and catalysis with particular attention to the production of general laboratory hardware, analytical facilities, reaction devices, and catalytically active substances. It also focuses on new and upcoming applications such as digital chemical synthesis, automation, and robotics in a synthetic environment. While discussing the contribution of this research area in the last decade, the current, future, and economic opportunities of additive manufacturing in chemical research and material development were fully covered.

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Section: Role Of 3-d Printing In Chemistry and Associated Fieldsmentioning

confidence: 99%

“…Recently, Halevi et al . prepared a 3- D -printed catalytic material consisting of 100% pure, self-standing nickel coordination polymer [ 98 ] using a modified digital light processing printer (DLP). The pictures of the printed MOFs are depicted in Fig.…”

Section: Role Of 3-d Printing In Chemistry and Associated Fieldsmentioning

confidence: 99%

Current and future trends of additive manufacturing for chemistry applications: a review

Alimi

Meijboom

2021

J Mater Sci

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“…Halevi et al. also recently published another interesting study based on a DLP 3D printing process, through which a freestanding 3D object, composed solely of a novel CP, was printed [53] …”

Section: Three‐dimensional Printed Materials Based On Coordination Bomentioning

confidence: 99%

New Promises and Opportunities in 3D Printable Inks Based on Coordination Compounds for the Creation of Objects with Multiple Applications

Maldonado

Amo‐Ochoa

2020

Chemistry A European J

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This review focuses on the usefulness of coordination bonds to create 3D printable inks and shows how the union of chemistry and 3D technology contributes to new scientific advances, by allowing amorphous or polycrystalline solids to be transformed into objects with the desired shape for successful applications. The review clearly shows how there has been considerable increase in the manufacture of objects based on the combination of organic matrices and coordination compounds. These coordination compounds are usually homogeneously dispersed within the matrix, anchored onto a proper support or coating the printed object, without destroying their unique properties. Advances are so rapid that today it is already possible to 3D print objects made exclusively from coordination compounds without additives. The new printable inks are made mainly with nanoscale nonporous coordination polymers, metal–organic gels, or metal–organic frameworks. The highly dynamic coordination bond allows the creation of objects, which respond to stimuli, that can act as sensors and be used for drug delivery. In addition, the combination of metal–organic frameworks with 3D printing allows the adsorption or selective capacity of the object to be increased, relative to that of the original compound, which is useful in energy storage, gas separation, or water pollutant elimination. Furthermore, the presence of the metal ion can give them new properties, such as luminescence, that are useful for application in sensors or anticounterfeiting. Technological advances, the combination of various printing techniques, and the properties of coordination bonds lead to the creation of surprising, new, printable inks and objects with highly complex shapes that will close the gap between academia and industry for research into coordination compounds.

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“…The group also developed a porous (surface area of 53.32 ± 23.00 m 2 g -1 , pore size of 35.90 24.80 Å) material 3D-printed ± by DLP. 201 In this purpose, the authors made use of Ni 2+ complexes carrying acrylamide ligands. The analysis of the crosslinked materials evidenced that coordination sphere of the metal-centres remained unchanged through photopolymerisation.…”

Section: Metal Organic Famework Based Networkmentioning

confidence: 99%