Synthesis, structure and bonding of a digold complex with bridging triphenylstannyl ligands

Adams, Richard D.; Wong, Yuen Onn; Zhang, Qiang

doi:10.1016/j.jorganchem.2015.01.021

Cited by 3 publications

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“…16 Structural characterisation of organostannyl-coinage metal complexes, however, is limited to a very small number of N-heterocyclic carbene (NHC) supported copper(I) complexes 19,20 alongside a single phosphine supported gold(I) system. 21 Sadighi and co-workers reported the first structurally authenticated copper stannyl, synthesising (IPr)CuSnPh 3 (IPr = 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene) by the deprotonation of Ph 3 SnH by (IPr)CuX (X = H, O t Bu). 19 These sparse examples are matched by a correspondingly limited, although intriguing, set of reactivity studies.…”

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The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes

et al. 2022

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The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes

et al. 2022

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Coordination Chemistry of Heavier Group 13 and 14 Ligands in Transition Metal Complexes

Gamage¹,

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2021

Comprehensive Coordination Chemistry III

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Coordination chemistry of stannylene-based Lewis pairs – insertion into M–Cl and M–C bonds. From base stabilized stannylenes to bidentate ligands

et al. 2018

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The coordination chemistry of intramolecular stannylene phosphorus Lewis pairs incorporated into four membered ring systems is presented. Previously reported coordination chemistry of stannylene and phosphorus towards palladium(0) is extended by using Pd(nbe) as a precursor, yielding co-ligand free complexes. An equilibrium of one or two stannylene phosphorus ligands coordinated to Pd(0) was observed with tin acting either as a donor or an acceptor towards palladium. Furthermore, the reactions with transition metal(i) chlorides, [(cod)IrCl], [(cod)RhCl] and MeSAuCl are reported. They proceed via insertion of stannylene into the M-Cl bonds, yielding metal complexes with chelating stannide phosphorus ligands. For gold, a dinuclear complex with bridging P-Sn ligands was formed. Furthermore, the reaction of a P → Sn Lewis pair in a three membered ring system with (cod)PtMe is reported.

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Synthesis, structure and bonding of a digold complex with bridging triphenylstannyl ligands

Cited by 3 publications

References 51 publications

The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes

The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes

Coordination Chemistry of Heavier Group 13 and 14 Ligands in Transition Metal Complexes

Coordination chemistry of stannylene-based Lewis pairs – insertion into M–Cl and M–C bonds. From base stabilized stannylenes to bidentate ligands

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