Synthesis, structural investigations and DNA cleavage properties of a new water soluble Cu(II)–iminodiacetate complex

Synthesis, structural investigations, and cytotoxic evaluation of a half‐sandwich Ru(II)‐arene complex

“…An intense peak observed at 298 nm indicated the metal to ligand charge transfer (MLCT) transitions while absorption bands observed at 420 and 534 nm were attributed to d–d transitions, namely, β–(Ru II d xz ) → β–(Ru II d x 2 − y 2 ) and β–(Ru II d xz ) → β–(Ru II d yz ), respectively (Figure S4). [ 32 ]…”

“…, respectively ( Figure S4). [32] The Hirshfeld surface analysis was used to evaluate the distributions of electronic densities along with the intermolecular interactions within the crystal structures of complex 1. The Hirshfeld surface analysis was examined in terms of d norm surface and 2D fingerplots that are crucial to study the surface characteristics and identification of close intermolecular interactions.…”

Synthesis of New Derivatives of BEDT-TTF: Installation of Alkyl, Ethynyl, and Metal-Binding Side Chains and Formation of Tris(BEDT-TTF) Systems

“…It can act as tridentate dianion (L 2− ) binding by two oxygens and nitrogen; be protonated once (HL − ), on nitrogen or oxygen, and act as a bidentate or tridentate monoanion, respectively; or be protonated twice and coordinate as a neutral ligand (H 2 L). Such behaviours are seen with simpler N-alkylated iminodiacetate ligands [41][42][43]. It can also act as just a bridging ligand [44].…”

Adsorptive avidity of Prussian blue polypyrrole nanocomposite for elimination of water contaminants: a case study of malachite green and isoniazid

“…[16][17][18] However, the impact of transition metal complex doping on polymers for adsorption applications has been scarcely studied. In continuation of our interests in applications of transition metal complexes, [19][20][21] especially as dopants in conducting polymer matrix for dielectric properties and water treatment applications, 22,23 we explore here their structure-activity response for the adsorption of dye and antibiotic contaminants under environmentally viable conditions (pH 7, and 20 1C). The systematic adsorption study was also envisaged in the synergistic conversion of toxic nitrophenol (4-NP) to non-toxic aminophenol using NaBH 4 as a reducing agent in the absence of light, via combined adsorptive and catalytic steps.…”