Synthesis, structural characterization and quantum chemical calculations on 1-(isomeric methylbenzoyl)-3-(4-trifluoromethylphenyl)thioureas

Crystal structure of bis(2-((allylcarbamothioyl)imino)-4-methylthiazol-3-ido-κ2 N,S)palladium(II), C16H20N6PdS4

“…Many reports have documented the ability of thioureas to coordinate transition metals such as Ni(II), Cu(II), Co(II), Fe(III) [5,6], Zn(II) [7], Pd(II) [8], and Ru(II) [9]. Their diversified use has received attention by various scientific communities including medical [10], analytical chemistry and metallurgy fields [11]. To name a few, they have been used in antiviral [12,13], anti-HIV [14], antimicrobial, antitumor, anti-inflammatory [15], and insecticidal substances [16].…”

Discotic Liquid Crystals Based on Cu(I) Complexes with Benzoylthiourea Derivatives Containing a Perfluoroalkyl Chain

“…Several regions of the FTIR spectra, recorded in KBr discs, are of interest for supporting the coordination via the sulfur atom: 3200-3400 cm −1 for ] N-H frequencies, 1500-1700 cm −1 for strong ] C�O and ] C-N frequencies, and finally, 1100-1250 cm −1 where strong absorption bands assigned to a combination of ] C-N and ] phenyl stretching frequencies can be found [54][55][56][57][58]. For example, the intensity and the position of the carbonyl stretching ] C�O at ∼1665 cm −1 are essentially the same in the IR spectra of 2a and 2b as in the free ligand 1. e medium intense band at 1350 cm −1 in the IR of ligand 1, assigned to ] C�S , is absent in the IR spectra of copper(I) complexes [34].…”

Synthesis, crystal structure, hydrogen bonding interactions analysis of novel acyl thiourea derivative

“…On the other hand, acyl thiourea derivatives are widely applied in recent decades, such as heterocyclic synthesis intermediate, non‐ionic surfactants, organocatalysts, etc. Further, due to the unique structure of CONHCSNH in the structure of the acyl thiourea compound, it has a wide range of biological activities, such as antiviral, antimicrobial, herbicidal, antitumor, anti‐inflammatory, and fungicidal properties . However, an increasing number of people are engaged in researching anticancer drugs as cancer cases have become more diverse and complex.…”